A comprehensive odor and odorant concentration database was formulated by a monitoring study in the occupational environment of a post-digestion dewatering building. The presence of odorants in the building are at concentrations below occupational exposure limits but higher than odor detection threshold values. This finding indicates that reducing odorant concentrations below exposure limits does not assure an odor-free environment. A model is formulated and validated for this dewatering building associating odor perception with concentrations of total sulfur compounds and relative humidity and is used for prediction of indoor odor concentrations under various conditions. Odor and odorant emission rates as the strength of sources are input variables of the indoor air quality model. In this study, odor and odorant emission rates from freshly dewatered biosolids in a dewatering building were measured using two widely used dynamic methods: the USEPA flux chamber and wind tunnel, and results from the two methods are not significantly different. Comparison of the two methods indicates that both methods can be used to estimate odor and odorant emission rates but the most effective and efficient method depends on prevailing environmental conditions. The ORfC established based on the comprehensive odor and odorant concentration database for this dewatering building is 13D/T (dilution to threshold). This index is used to evaluate seven control strategies recommended to reduce odor levels. If indoor odor concentrations in the occupational environment exceed the ORfC, then the hazard of odor exposures is unacceptable. Deterministic results of this study indicate that if appropriate control strategy is applied, odor concentration in the dewatering building would reach to below levels that cause unnecessary stress and other effects. The control strategy focus of this work is reduction of the indoor odor perception. But indoor control strategies must not cause outdoor odor problems to surrounding residential areas. Therefore, the potential impact of the control strategy recommended is also investigated in this thesis using the US EPA recommended air dispersion modeling AERMOD. Predictions of hydrogen sulfide concentrations at surrounding areas of the plant indicate that only one strategy, which proposes to add a new exhaust system in the dewatering building, would cause the ambient hydrogen sulfide concentration to be 7% higher than the odor detection threshold; other six strategies would not induce odor annoyance to surrounding areas. Acute and long-term ambient hydrogen sulfide exposure limits based on human health and irritation effects would not be violated under any of the seven control strategies.
Ph.D. in Environmental Engineering, May 2011
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