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(341 - 360 of 4,071)
Pages
- Title
- Structural considerations in the design of modern abattoirs and cold storage warehouses
- Creator
- Edlund, Lawrence L
- Date
- 2009, 1920
- Publisher
- Armour Institute of Technology
- Description
-
http://www.archive.org/details/structuralconsid00edlu
Thesis (B.S.)--Armour Institute of Technology
- Title
- SITUATING FANS' SOCIAL MEDIA PRACTICES IN THE CONTEXT OF FAN STUDIES
- Creator
- Rao, Xi
- Date
- 2015, 2015-05
- Description
-
This paper explores how TV fans use social media. By revtewmg academic perspectives on fandom ofTV shows and social media in past several...
Show moreThis paper explores how TV fans use social media. By revtewmg academic perspectives on fandom ofTV shows and social media in past several decades, this paper discusses the way that audiences react to TV shows using the affordance of social media. At the begirming, this article traces the image, activities, and meaning of fandom. Fans were portrayed as deviant creatures until the late 80s. This image was clarified when people looked into fans and their creative works. Scholars realized that fans productively generated creative products based on the given materials, which reflected the social experience of the creators. Therefore, fandom was soon understood as a way of fans to resist the dominant culture in the society. Later on, social media offer fans an immediate, widespread platform to contribute to the TV conversation. With this platform, normal fans show up. Different from productive fandom, median fans are less active in making new meanings of the TV program. Interestingly, a large number of TV audiences are using social media during the broadcast, participating in the discussion of shows. This evidences the convergence of the traditional media, TV, and the new media, social media. It is also found that comments of TV viewers on social media in turn, influence the content of the TV show. Rather than merely spectators, fans are a part of the TV production. As a special case, gender is discussed from the perspective of fandom. Female composers dominant the fan-writing world. Study the producers and products of fan fiction may provide valuable insights into gender dilemmas in the real world. At the end of this essay, 1 summarize how social media atTect the participation of TV fans and discuss remaining questions worthy of future research. Since fandom becomes ubiquitous in the social media age, it is possible to explore fandom as a way to better understand our daily life.
M.S. in Information Architecture, May 2015
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- Title
- ASYMPTOTIC SIMILARITY IN TURBULENT BOUNDARY LAYERS
- Creator
- Duncan, Richard D.
- Date
- 2011-05-10, 2011-05
- Description
-
The turbulent boundary layer is one of the most fundamental and important applications of fluid mechanics. Despite great practical interest...
Show moreThe turbulent boundary layer is one of the most fundamental and important applications of fluid mechanics. Despite great practical interest and its direct impact on frictional drag among its many important consequences, no theory absent of significant inference or assumption exists. Numerical simulations and empirical guidance are used to produce models and adequate predictions, but even minor improvements in modeling parameters or physical understanding could translate into significant improvements in the efficiency of aerodynamic and hydrodynamic vehicles. Classically, turbulent boundary layers and fully-developed turbulent channels and pipes are considered members of the same “family,” with similar “inner” versus “outer” descriptions. However, recent advances in experiments, simulations, and data processing have questioned this, and, as a result, their fundamental physics. To address a full range of pressure gradient boundary layers, a new approach to the governing equations and physical description of wall-bounded flows is formulated, using a two variable similarity approach and many of the tools of the classical method with slight but significant variations. A new set of similarity requirements for the characteristic scales of the problem is found, and when these requirements are applied to the classical “inner” and “outer” scales, a “similarity map” is developed providing a clear prediction of what flow conditions should result in self-similar forms. An empirical model with a small number of parameters and a form reminiscent of Coles’ “wall plus wake” is developed for the streamwise Reynolds stress, and shown to fit experimental and numerical data from a number of turbulent boundary layers as well as other wall-bounded flows. It appears from this model and its scaling using the free-stream velocity that the true asymptotic form of u′2 may not become self-evident until Re ≈ 275, 000 or δ+ ≈ 105, if not higher. A perturbation expansion made possible by the novel inclusion of the scaled streamwise coordinate is used to make an excellent prediction of the shear Reynolds stress in zero pressure gradient boundary layers and channel flows, requiring only a streamwise mean velocity profile and the new similarity map. Extension to other flows is promising, though more information about the normal Reynolds stresses is needed. This expansion is further used to infer a three layer structure in the turbulent boundary layer, and modified two layer structure in fully-developed flows, by using the classical inner and logarithmic profiles to determine which portions of the boundary layer are dominated by viscosity, inertia, or turbulence. A new inner function for U+ is developed, based on the three layer description, providing a much more simplified representative form of the streamwise mean velocity nearest the wall.
Ph.D. in Mechanical and Aerospace Engineering, May 2011
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- Title
- Laboratory Notebook 107
- Creator
- Cooper, Kerri, Lee, Alvin, Slade, Peter
- Date
- 2010-09-10T18:26:27Z
- Description
-
Determining ozone's optimal conditions (contact time, concentration)
- Title
- High-order cumulants from the 3D O(1) and O(4) spin models, Proceedings of the XLIII International Symposium on Multiparticle Dynamics
- Creator
- Pan, Xue, Wu, Yuafang, Chen, X. S., Chen, Lizhu
- Date
- 2013-09-15, 2013-09-15
- Publisher
- IIT Press
- Description
-
We simulate the 3D O(1) (Ising) and O(4) spin models by the Monte Carlo method. Interesting high-order cumulants from the 3D Ising and O(4)...
Show moreWe simulate the 3D O(1) (Ising) and O(4) spin models by the Monte Carlo method. Interesting high-order cumulants from the 3D Ising and O(4) universality classes are presented and discussed. They all show the non-monotonic or sign change behavior. The critical behavior is instructive to that of the high-order cumulants of the net baryon number in the QCD phase transitions. Maybe it’s difficult to distinguish the universality classes by the high-order cumulants in the heavy ion collisions.
Sponsorship: IIT College of Science, High Energy Physics Division of Argonne National Laboratory
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- Title
- PA 508 Library Instruction
- Creator
- Ahrens, Aric G.
- Date
- 2010-01-15, 2010-01-15
- Description
-
This PowerPoint presentation was given to the Chinese contingent of the Master of Public Administration Graduate Program during Spring...
Show moreThis PowerPoint presentation was given to the Chinese contingent of the Master of Public Administration Graduate Program during Spring Semester 2010. It covers basic research and library skills.
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- Title
- Cavity Resonance Suppression Using Miniature Fluidic Oscillators
- Creator
- Raman, G., Raghu, S.
- Date
- 2004-12
- Publisher
- American Inst Aeronaut Astronaut
- Title
- Nonlinear Interactions as Precursors to Mode Jumps in Resonant Acoustics
- Creator
- Panickar, P., Srinivasan, K., Raman, G.
- Date
- 2005-09
- Publisher
- American Inst Physics
- Description
-
This paper examines instability mode switching in various supersonic jet configurations that involve resonant acoustics. Resonant acoustics...
Show moreThis paper examines instability mode switching in various supersonic jet configurations that involve resonant acoustics. Resonant acoustics includes situations where flow instabilities are enhanced by feedback. The pressure spectra in such situations are rich in multiple modes, and mode switching can occur rather unpredictably. Our experiments reveal that mode switching and the number of nonlinear interactions are interconnected and this number increases just prior to a mode switch. We quantified nonlinear interactions by counting the number of such interactions occurring over a threshold level in the nonlinear cross-bicoherence spectrum and confirmed that nonlinear interactions are precursors to mode jumps. Further, this result was found to be independent of the threshold level. Moreover, if more than one instability mode coexisted, the decay of one and the persistence of the other caused a similar increase in nonlinearities. On the other hand, if there was no mode switch, the nonlinearities remained at comparable limits over the entire operating range. The latter part of the work focused on why difference interactions significantly outnumbered sum interactions in the spectra of shock-containing resonant flows. Using linear stability calculations it is shown that most of the difference interactions that occurred had a positive spatial growth rate and were, hence, unstable. In contrast, a majority of the sum interactions lay outside the amplified region which indicated that they tend to decay spatially. (c) 2005 American Institute of Physics.
http://dx.doi.org/10.1063/1.2008995
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- Title
- Mycoflora of Indoor Dust and Alternaria Alternata Growth on Building Materials
- Creator
- Simpson, Stacy
- Date
- 2011-10-27, 2011-12
- Description
-
Alternaria alternata, a clinically significant mold species is associated with allergic disease and asthma. An indoor growth of A. alternata...
Show moreAlternaria alternata, a clinically significant mold species is associated with allergic disease and asthma. An indoor growth of A. alternata may initiate atopic symptoms, accumulate in dusts, and discolor and deteriorate indoor building materials. Environmental control should be the initial approach to maintain a healthy indoor environment and manage allergic diseases. The current thesis investigated indoor dusts from various environments for mold spores and Alt a 1. Laboratory studies were carried out to determine if or which commercially available mold-resistant treatments and building materials could efficiently decrease A. alternata growth and Alt a 1. The mycoflora of indoor dusts was microscopically examined and the clinically significant allergen from A. alternata, Alt a 1 was measured in sampled dusts using a monoclonal anti-recombinant Alt a 1 (rAlt a 1) enzyme linked immuno-sorbent assay (ELISA). To investigate building material susceptibility untreated, mildew-resistant painted, and commercially available biocide treated building materials were inoculated with A. alternata spores, incubated in a humidity controlled chamber, and compared for mold growth and the presence of Alt a 1. A photo-monitoring technique was used to survey and determine mold growth surface area coverage. Alt a 1 immuno-reactivity of superficial mold growths was analyzed with the ELISA. The microscopic speciation of mold spores indicated that a diverse mycoflora can be found in indoor dusts. Although A. alternata was found in low concentrations in a few samples, Alt a 1was below the limit of detection. Nevertheless, mold spores can significantly contribute to the complexity of indoor dusts. A. alternata grew on all tested building materials but both painted and treated building materials inhibited mold growth in comparison to untreated samples. Not all material surfaces contained detectable levels of Alt a 1. Comparisons between untreated and painted building material groups indicated that a significant difference between the Alt a 1 accumulation content could not be established. To establish a standard sampling protocol and reliable prevention methods for mold contamination and exposure more knowledge about indoor molds must be gained.
M.S. in Environmental Engineering, December 2011
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- Title
- Mixer-ejector Wall Pressure and Temperature Measurements Based on Photoluminescence
- Creator
- Taghavi, R.r., Raman, G., Bencic, Tj
- Date
- 2002-04
- Publisher
- American Inst Aeronaut Astronaut
- Description
-
Ejector side-wall pressure distribution is a key indicator of supersonic jet-mixer-ejector performance. When documenting pressure patterns on...
Show moreEjector side-wall pressure distribution is a key indicator of supersonic jet-mixer-ejector performance. When documenting pressure patterns on an ejector wall using pressure-sensitive paint (PSP), one has to consider temperature variations caused by the supersonic jet flow within the ejector because these can cause significant local errors in the PSP results. If the temperature sensitivity of PSP is not corrected for in complex internal supersonic flows, large localized errors could contaminate the results. In the present work, temperature-sensitive paint maps the temperature distribution on the ejector wall and corrects PSP results point-by-point for temperature sensitivity. The experiments were conducted on multijet supersonic mixer-ejector configurations with straight, convergent (6-deg), and divergent (6-deg) side walls. A comparison of corrected and uncorrected PSP readings shows that at M-j = 1.55, the error with respect to true data from static pressure ports can be reduced from 4.98 to 2.84% for the case of a simple ejector with parallel walls. For the complex 6-deg convergent ejector at M-j = 1.39, the error reduces by almost an order of magnitude (from 20.83 to 2.66%). Our results indicate that the use of this correction technique can significantly reduce PSP errors in complex internal supersonic flow situations.
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- Title
- MECHANICAL PROPERTIES AND SINTERING MECHANISMS OF POWDER METALLURGY TI6AL4V
- Creator
- Xu, Xiaoyan
- Date
- 2013, 2013-05
- Description
-
Titanium has been identified as one of the key materials with a high strength to weight ratio that can reduce the weight of components and...
Show moreTitanium has been identified as one of the key materials with a high strength to weight ratio that can reduce the weight of components and thereby reduce energy consumption. Single press and sinter as a powder metallurgy technique has the potential to provide cost effective components. Armstrong prealloyed Ti6Al4V, HDH prealloyed Ti6Al4V, HDH blended Ti6Al4V powder and their mixtures were pressed and sintered at different conditions. The chemistry, mechanical and microstructural properties have been investigated to establish optimum processing parameters. Sintered parts were sent to Oshkosh Truck to test and compared with aluminum and steel parts. The Titanium and Ti6Al4V parts were successfully applied and tested. All the specimens passed the load test without failures. The sintering mechanisms of Armstrong prealloyed Ti6Al4V powder were investigated. At relative sintered densities of 75% to 90% (around 900°C), surface diffusion cooperate with grain boundary diffusion, which leads to densification of the powder compact. Around 900°C, grain boundary diffusion controls the sintering process. At 1000°C, boundary diffusion made little contribution to the densification of the Ti6Al4V powder compact. Above 900°C and below 91% sintered density, boundary diffusion controls sintering. Lattice diffusion dominates the densification process at higher temperatures (1100°C~1300°C). The sintering of master alloy blended Ti6Al4V powder has been investigated in order to elucidate the mechanism of sintering. Both blended powder compacts and diffusion couples were investigated using backscattered imaging and energy xvi dispersive analysis to determine the phases present and diffusion path on sintering at 1000ºC and 1100ºC. It is shown that transient liquid phase sintering does not occur and the reason for the rapid sintering of this material is due to enhanced diffusion kinetics resulting from a combination of the concentration gradient and stress induced by a phase transformation in the ternary system.
PH.D in Materials Science and Engineering, May 2013
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- Title
- WEB-BASED CONTEMPORANEOUS DELAY ANALYSIS
- Creator
- Pektas, Murat
- Date
- 2011-11-22, 2011-12
- Description
-
The construction industry is fragmented due to the many stakeholders and the diverse phases involved in a construction project. On time,...
Show moreThe construction industry is fragmented due to the many stakeholders and the diverse phases involved in a construction project. On time, within budget, with required quality are essentials of a successful project. However, most construction projects are faced with delays, which obstruct success. To recover the damage caused by delays, both the delays and the parties responsible for them should be identified accurately. Daily window delay analysis outperforms other delay analysis methods, but it requires intensive day-by-day information. The information flow among the project stakeholders must be smooth and speedy at all stages of the production process not only to achieve the basic project objectives but also to let project stakeholders recognize the delays and the parties responsible for them in order to recover time and cost. The Internet is attractive for transferring information promptly and economically with no regional or temporal borders. To merge the power of the Internet and to ease time consuming delay analysis, a web-based application is proposed to analyze delays effectively and contemporaneously, to reduce time and cost, and to provide historical data. The application considers the day-by-day variation in critical path(s) during the project life cycle. The application gives accurate and repeatable results for apportioning project delays, accelerations and decelerations among involved parties. The manual effort required by traditional systems is minimized with the application’s simple, easy to use, yet effective and highly automated features. Moreover, the database structure of the application is designed to store and manage more than one project at a time to let its users calculate the overall performance of the company including all projects, and to calculate average durations for activities that can come up in future projects.
M.S. in Civil Engineering, December 2011
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- Title
- Empirical modeling of systems with output multiplicities by multivariate additive NARX models
- Creator
- Decicco, J., Cinar, A.
- Date
- 2000-06
- Publisher
- AMER CHEMICAL SOC
- Description
-
Multivariable additive NARX (nonlinear autoregressive with exogenous inputs) modeling of process systems is presented. The model structure is...
Show moreMultivariable additive NARX (nonlinear autoregressive with exogenous inputs) modeling of process systems is presented. The model structure is similar to that of a generalized additive model (GAM) and is estimated with a nonlinear canonical variate analysis (CVA) algorithm called CANALS. The system is modeled by partitioning the data into two groups of variables. The first is a collection of future outputs, and the second is a collection of past input and outputs and future inputs. This approach is similar to linear subspace state-space modeling. An illustrative example of modeling is presented on the basis of a simulated continuous chemical reactor that exhibits multiple steady states in the outputs for a fixed level of the input.
Endnote format citation for DOI:10.1021/ie9906464
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- Title
- A METHODOLOGY FOR MAJOR BUS ROUTE RESCHEDULING TO IMPROVE TRANSIT PERFORMANCE
- Creator
- Lu, Xi
- Date
- 2012-08-01, 2012-07
- Description
-
In a period of growing transit operating deficits, increasing attention and concern is being directed at both the decreasing levels of...
Show moreIn a period of growing transit operating deficits, increasing attention and concern is being directed at both the decreasing levels of productivity of transit systems in general and the broad differences in measured service performance compiled for various transit systems. The purpose of this study is an assist public transit managers by providing them with a mathematical technique to analyze the efficiency with which serviced is produced and the effectiveness with which it is consumed. By providing the analysis model which not requires an extensive amount of data, the operator can have tool for decision-making of profit and market growth. Thus, transit managers will be able to access the performance of the agency and areas where improvements can be realistically achieved. Using the urban operation of the Chicago Transit Authority, a transit performance model is developed to analysis efficiency and effectiveness of the city's bus system. As the system exists, there are 144 bus routes start and end, frequency of dispatching buses and ridership changes from Weekdays and Weekend, peak hour and off-peak hour. In many of these routes, vehicles are used inefficiently and ineffectively, only a few passengers carried in some routes in off-peak hour, yet in other routes through the Central Business District (CBD) area, there are always not enough buses in peak hour. Also, some routes cannot provide enough on-time arrival service and some special group like elderly and handicapped cannot receive enough service in certain area. The goal of case research is to determine to understand the transit performance of Chicago Transit Authority and to select the optimal improvement projects to maximize the performance in term of economy and social equity.
M.S. in Civil Engineering, July 2012
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- Title
- SUSTAINABLE NEW CITY MENTOUGOU, CHINA
- Creator
- Yin, Lu
- Date
- 2013-04-30, 2013-05
- Description
-
This thesis will demonstrate one of the first urban models for the future of China’s growth. The Urban Operating System and GPS make the smart...
Show moreThis thesis will demonstrate one of the first urban models for the future of China’s growth. The Urban Operating System and GPS make the smart city smarter by linking up networks of billions of distributed sensors, systems, and intelligence across urban environments via city-scale operating systems. Personal Rapid Transit system runs everywhere and it is accessed and ordered by smart phone. Green belt is the medium that links all the natural area and parks in the city which become the core element in the city because it plays the most important role. Two types of transportation system including the Meglev for 10 minute access to Beijing and the PRT system for all internal urban mobility. The population of the new city is 80000. 80% of the people live here and work here, 20% of the people live here but work in Beijing. 30% of the people will use PRT system everyday. All the city blocks are mixed-use blocks. There are several types of residential buildings including mid-rise, high-rise and Beijing traditional courtyard house. This sustainable new city provides quality of lift to all the people live in the city.
M.S. in Architecture, May 2013
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- Title
- DAMAGE DETECTION OF STRUCTURES USING INTERVAL FINITE ELEMENT METHOD
- Creator
- Venkitaraman, Shyamala
- Date
- 2012-04-16, 2012-05
- Description
-
Health assessment and damage detection for existing structures is an essential procedure for their safe and reliable operation so that any...
Show moreHealth assessment and damage detection for existing structures is an essential procedure for their safe and reliable operation so that any catastrophic failure may be prevented in a timely manner. However, results obtained from a health assessment of a structure possess uncertainties in measurements, system properties and loads. Furthermore, the conventional deterministic structural analyses are incapable of considering these uncertainties, thereby resulting in error when estimating the state of health of a structure. Interval (unknown-but-bounded) representation is one method to quantify uncertainty in a physical system. Using an interval variable, the uncertain parameter is bounded between extreme values. In this work, a new method for damage assessment of structures is developed that utilizes the results from structural health assessment as uncertain input parameters in an interval finite element analysis scheme. This method, due to its capability of considering uncertainties, offers a more robust process for estimating the possible existence of damage and overall health of the structure. As an illustrative example, the method is applied for a failed sign support structure. First, the structure's response from previous health assessment procedure was used to construct uncertain interval responses. Then using these interval responses as input parameters, an interval finite element method was performed. The results of the analysis verify and correlate with the failure location of the actual structure. Moreover, the lifetime assessment of the structure obtained from this method is the lower bound of, and correlates with the actual failure time of the structure.
M.S. in Civil Engineering, May 2012
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- Title
- Laboratory Notebook 112
- Creator
- Zhang, Zhe, Varelis, Peter
- Date
- 2010-03-09T22:34:24Z
- Description
-
This laboratory notebook relates to the "Heat Stability of Ricin in Phosphate Buffer System" project with Peter Varelis as the Principle...
Show moreThis laboratory notebook relates to the "Heat Stability of Ricin in Phosphate Buffer System" project with Peter Varelis as the Principle Investigator.
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- Title
- PARADIGM SHIFT IN REMOTE EDUCATION FOR THE LABORATORY: A SOCIAL APPROACH TO DISTANCE LEARNING
- Creator
- Hanley, Richard
- Date
- 2011-12, 2011-12
- Description
-
With modern telecommunication tools the ability for two individuals to work together remotely has greatly improved. Moreover, there have been...
Show moreWith modern telecommunication tools the ability for two individuals to work together remotely has greatly improved. Moreover, there have been great strides made to improve handling medium to large groups of people in real time in remote settings, viz. the teleconference and webinar. However, the status of remote tools for laboratory environments where there is significant hardware and the individuals are more likely to talk amongst themselves in irregular patterns is not nearly as well studied. This thesis examines the way most laboratories in electrical engineering are setup, and creates a model for how to create a remote environment for distance learning. It then discusses the current state of the art, and how such an implementation of the model can be made with such tools. Finally a usability study of the implementation is examined. The primary result of the usability study is that when moving to a remote environment the social paradigm that students and instructors use is likely to change, and simply working on creating a virtual mirror to the laboratory may not work in the future.
M.S. in Electrical Engineering, December 2011
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- Title
- Development of High Bandwidth Powered Resonance Tube Actuators with Feedback Control
- Creator
- Raman, G., Khanafseh, S., Cain, A. B., Kerschen, E.
- Date
- 2004-01-22
- Publisher
- Academic Press Ltd Elsevier Science Ltd
- Description
-
A high bandwidth powered resonance tube (PRT) actuator potentially useful for noise and flow control applications was developed. High...
Show moreA high bandwidth powered resonance tube (PRT) actuator potentially useful for noise and flow control applications was developed. High bandwidth allows use of the same actuator at various locations on an aircraft and over a range of flight speeds. The actuator selected for bandwidth enhancement was the PRT actuator, which is an adaptation of the Hartmann whistle. The device is capable of producing high-frequency and high-amplitude pressure and velocity perturbations for active flow control applications. Our detailed experiments aimed at understanding the PRT phenomenon are complemented by an improved analytical model and direct numerical simulations. We provide a detailed characterization of the unsteady pressures in the nearfield of the actuator using phase averaged pressure measurements. The measurements revealed that propagating fluctuations at 9 kHz were biased towards the upstream direction (relative to the supply jet). A complementary computational study validated by our experiments was useful in simulating the details in the region between the supply jet and the resonance tube where it was difficult to gather experimental data. High bandwidth was obtained by varying the depth of the resonance tube that determines the frequency produced by the device. Our actuator could produce frequencies ranging from 1600 to 15,000 Hz at amplitudes as high as 160 dB near the source. The frequency variation with depth is predicted well by the quarter wavelength formula for deep tubes but the formula becomes increasingly inaccurate as the tube depth is decreased. An improved analytical model was developed, in which the compliance and mass of the fluid in the integration slot is incorporated into the prediction of resonance frequencies of the system. Finally a feedback controller that varied both the resonance tube depth and spacing to converge on a desired frequency was developed and demonstrated. We are optimistic that numerous potential applications exist for such high bandwidth high dynamic range actuators. (C) 2003 Published by Elsevier Science Ltd.
http://dx.doi.org/10.1016/S0022-460X(03)00212-8
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- Title
- EUTECTIC γ(NI)/γ′(NI3AL)-δ(NI3NB) POLYCRYSTALLINE NICKEL-BASE SUPERALLOYS: CHEMISTRY, PROCESSING, MICROSTRUCTURE AND PROPERTIES
- Creator
- Xie, Mengtao
- Date
- 2012-12-03, 2012-12
- Description
-
Directionally solidified γ(Ni)/γ′(Ni3Al)-δ(Ni3Nb) eutectic alloys possess attrac- tive high temperature mechanical properties and were...
Show moreDirectionally solidified γ(Ni)/γ′(Ni3Al)-δ(Ni3Nb) eutectic alloys possess attrac- tive high temperature mechanical properties and were considered as candidate tur- bine blade materials. Currently, the properties of polycrystalline γ/γ′-δ alloys are of interest as they inherit many advantageous attributes from the directionally solidi- fied γ/γ′-δ alloys, including high volume fraction of reinforcing phases, exceptional thermal stability and resistance to segregation-induced defect formation. If these at- tributes are properly harnessed, these γ/γ′-δ eutectic alloys might provide a unique solution to the problems experienced by traditional γ/γ′ polycrystalline Ni-base su- peralloys. This thesis is therefore dedicated towards the development of a funda- mental understanding of this novel class of eutectic alloys from several important perspectives. To enrich our understanding of this alloy system, this thesis will first be focused on quantifying the specific effect of individual alloying element on this γ/γ′-δ eutectic system. A set of quaternary Ni-Cr-Al-Nb alloy compositions with increasing levels of Chromium(Cr) was designed to investigate the detailed influence of this element on the primary phase formation, solidus and liquidus temperatures and γ-δ eutectic morphology. The alloying effect of Tantalum(Ta), which shares many similarities to Niobium(Nb), was studied by designing a matrix of multi-component γ/γ′-δ alloy compositions with nominally the same overall (Ta+Nb) content but varying Ta/Nb ratios. Here, different solidification segregation and solid state partitioning behaviors of Ta and Nb in this γ/γ′-δ eutectic system will be discussed, as well as the influ- ence of Ta/Nb ratio on solidification characteristics and equilibrium/non-equilibrium phase volume fractions. Thermodynamic calculations using the Computherm Pandat database (PanNi7) were compared to experimental results in these investigations. The second part of this thesis will aim to provide a more general understand- xvii ing of the effect of various alloying elements, including Cr, Co, Al, Ti, Mo, W, Ta and Nb, on this γ/γ′-δ system. A large number of experimental γ/γ′-δ alloys covering a broad range of compositions was selected for the analysis in this study. Important alloy attributes, such as primary phase formation, overall δ volume fraction, phase transformation temperatures and ternary eutectic initiation, were quantitatively char- acterized as a function of individual alloying element concentrations or combined con- tent of more elements. Linear regression analysis was performed to reveal the relative effectiveness of these elements on this eutectic system. Meanwhile, an extensive com- parison between the experimental observations and Pandat predictions was provided to critically evaluate the strength and weakness of existing thermodynamic database model in predicting trends in this eutectic alloy system with substantially higher Nb content compared to traditional γ/γ′ superalloys. The last part of this thesis emphasizes the development of cast and wrought manufacturing processes for cast γ/γ′-δ eutectic alloys as a cost effective alternative to the powder metallurgy route. Hot rolling of workpieces encapsulated within a steel can was performed on a simple model cast γ/γ′-δ alloy (897) to stimulate the ingot to billet. The influence of different deformation levels on breaking down the dendritic structure and promoting fine and homogenized microstructure was investi- gated. The mechanical soundness associated with different microstructures generated by different hot rolling processes was compared via compression and creep testing. Microstructural parameters that contribute to better mechanical properties will be discussed.
PH.D in Materials Science and Engineering, December 2012
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