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- Title
- Polymorphic Network-on-Chip Datapath Architecture for Reconfigurable Computing Machines
- Creator
- Weber, Joshua
- Date
- 2012-04-18, 2012-05
- Description
-
Polymorphic processors have considerable advantages in performance over existing reconfigurable designs. Polymorphic processors combine the...
Show morePolymorphic processors have considerable advantages in performance over existing reconfigurable designs. Polymorphic processors combine the flexibility and ease of a general purpose processor with the performance optimizations made possible through reconfigurable arrays. Polymorphic processors provide all the ease of programming from a traditional general purpose processor while incorporating the significant performance gains that can be realized using reconfigurable arrays. Polymorphic processors can be categorized by the level of integration between the general purpose processor and the reconfigurable array. At coarse levels of integration, the processor and reconfigurable array execute independently and exchange data utilizing bus structures. These systems perform robustly for high level datadriven optimizations, allowing large segments of processing to be quickly performed on fast reconfigurable resources. However, the overhead of data transfer between the processor and array limits the benefit to fine grained optimizations. Other architectures attempt a tight coupling of reconfigurable arrays, placing them within the processor as reconfigurable coprocessors and functional units. This technique allows fine grained optimizations of small scale, highly repeated computations, but finds it difficult to replicate the gains made in large coarse grained optimizations. To achieve an even more tightly coupled design than any prior work, the fundamental architecture of the processor is changed. The datapath of the processor is eliminated and replaced with a network-on-chip communications framework. This framework connects a system of reconfigurable arrays. Some of these reconfigurable blocks are tasked with execution of standard, general purpose processor computations, emulating the standard pipeline stages of a SPARC processor. Additional reconfigurable blocks are available to the end-user to incorporate custom application specific optimizations. This new polymorphic NoC datapath (PolyNoC) processor is able to provide a more tightly integrated architecture with significant performance advantages. The PolyNoC processor is able to incorporate both fine and coarse grained optimizations, producing a polymorphic processor able to provide performance improvements for a wide range of target applications. This thesis presents the architectural design of the PolyNoC processor. The unique design constraints resulting from the use of the NoC as a datapath will be fully explored. The impact of these constraints will be incorporated into the design of a suitable NoC for the PolyNoC processor. A cycle-accurate simulator of the PolyNoC processor has been constructed. This simulator is used to examine the performance of the PolyNoC processor when executing unmodified, industry standard benchmark programs. To demonstrate the advantages of application specific extensions to the processor, accelerators are added for each benchmark. The performance of the Poly- NoC processor is promising.
Ph.D. Computer Science, May 2012
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- Title
- A SPECTRAL ELEMENT SOLVER FOR SIMULATING TURBULENT FLOWS IN COMPLEX GEOMETRIES
- Creator
- Kandala, Sriharsha
- Date
- 2015, 2015-07
- Description
-
Flows in urban street canopies are quite complex both physically and geometrically and often unique to the specific canopy. Understanding the...
Show moreFlows in urban street canopies are quite complex both physically and geometrically and often unique to the specific canopy. Understanding the physics of these flows is important for various applications like prediction and control of dispersion in urban environments and efficient navigation of Micro-Air Vehicles (MAV) in gusty velocity fields among others. These flows are turbulent and the velocity fields are characterized by a wide range of spatial and temporal scales. Traditionally, given the exorbitant number of grid points required for accurate resolution of all flow features in computer simulations, experimental measurements supplemented with theory were the only feasible choice for understanding these flows. However with rapid increase in computing power and development of highly scalable algorithms to harness this power, numerical simulations are increasingly becoming feasible for higher Reynolds number flows. In the current work, flow in a model urban street canyon is studied using high-fidelity three-dimensional computational fluid dynamics simulations. Specsolve, a parallel spectral element solver capable of running parallel simulations utilizing thousands of processors, is developed for this purpose. The simulation domain used in this study consists of a 5 by 7 array of obstacles representative of a typical urban environment with the canyon aspect ratio corresponding to the skimming flow regime. These simulations do not use any turbulence model and are stabilized using a filtering procedure. Hot-wire data obtained from the wind tunnel experiments performed on an identical domain are used to prescribe realistic inflow boundary conditions upstream of the array. Numerical simulations were performed for cases where the flow is perpendicular to the array and with the flow at 15 degree angle of incidence. A grid resolution study is conducted to zero-in on the spectral element mesh required to resolve all important flow features for the 0 degree angle of incidence case. Mean velocity, coherent-structures and turbulence characteristics are used to describe the most important flow features in the domain. Streetwise evolution of flow is studied and the results indicate that flow reaches an equilibrium state by the third street.
Ph.D. in Mechanical and Aerospace Engineering, July 2015
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- Title
- POWDER CHARACTERIZATION AND PROCESS OPTIMIZATION FOR COLD COMPACTION AND SINTER APPLICATIONS OF COMMERCIALLY PURE TITANIUM POWDERS
- Creator
- Araci, Kerem
- Date
- 2011-08, 2011-07
- Description
-
Near net shape manufacturing using powder metallurgy (P/M) technology and processes can significantly reduce material waste and cost during...
Show moreNear net shape manufacturing using powder metallurgy (P/M) technology and processes can significantly reduce material waste and cost during component fabrication. This study includes all the efforts to evaluate near net shape consolidation processes utilizing several different commercially pure titanium (CP-Ti) powders, focusing on the one produced by Armstrong Process® technology. Powder characteristics were studied in terms of morphology, particle size distribution, apparent and tap densities, and chemistry. Desired particle size distributions and higher powder densities were observed for HDH powders, while unique coral-like morphology was examined for the Armstrong Process® powder. Ball milling of the Armstrong Process® powder was systematically investigated by evaluating the impact on the particle size distribution, powder density and chemistry. Cold-uniaxial compaction of the milled powders was also evaluated in terms of theoretical density and green strength as a function of compaction pressure and lubrication techniques. Green densities were varied from 79 % to 91% for different powder compacts in different compaction conditions. Excellent green compaction of 145 MPa was approached by green compacts of Armstrong Process® powder. Sinter processing of the green compacts was investigated to approach relatively advanced tensile and flexural properties as a function of process temperature, time and heating rate. Near net-shape components which were fabricated by pressing and sintering were shown to achieve near-full densification with up to 97% of the theoretical density. Properties of P/M materials after the consolidation process were characterized and compared to those of conventionally produced materials.
M.S. in Materials Science and Engineering, July 2011
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- Title
- DEVELOPMENT OF ADVANCED PACKAGING, FABRICATION AND RELIABILITY METHODS FOR SUBMINIATURE IMPLANTABLE NEURAL PROSTHESES
- Creator
- Kim, Taehyung
- Date
- 2011-08, 2011-07
- Description
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The main purpose of the present thesis is to study the critical reliability issues of polymeric encapsulated electronic devices for visual...
Show moreThe main purpose of the present thesis is to study the critical reliability issues of polymeric encapsulated electronic devices for visual prosthesis. Visual prosthesis has been compatibly studied over twenty years in many professional research labs. The electric design of circuit for the visual prosthesis has been well studied so far. However, the device packaging design and reliability have been not studied extensively. In particular, failure analysis and reliability using non-hermetic packaging for long lifetime visual prosthesis have been poorly studied. The first step of the research for this thesis was to create a mechanical design of a visual prosthesis prototype. The prototype device was created by fabricate a multi-layer structure consisting of electrodes, substrate, and integrated circuit chip with silicone encapsulated packaging. The interconnection between the chip and electrodes used Au wire and Al bonding pad. The prototype devices were tested in a liquid water. This water environment is not a common reliability test for commercial electronic packaging. Relative humidity testing is a common and widely used testing methods, but the visual prosthesis device cannot be applied to gas phase relative humidity testing due to the environment condition. Water absorption in polymeric material in the liquid water is higher than in the vapor water. After water penetrated interconnection interface, the Au-Al intermetallic compound becomes oxidized and generates bonding die open failure. From these unusual testing results, we were conformed the failure mechanism and predicted the lifetime using Au-Al imtermetallic growth pattern and oxidation. Additional discussions include transition metal ions in CSF to expect the other failure mechanisms. Wafer and packaging level xiii failure mechanisms by Cu and Fe ions are also discussed in this thesis. The end of this thesis discuss possible fabrication processing to protect overall external environment effects for polymeric packaging visual prosthesis. Overall this thesis study, which uses polymeric packaging electronic devices for bio-implant research, concluded that devices may not make good reliability devices in the CSF environment. The corrosion, oxidation and metallization on or in metal surfaces and interconnection interfaces should continually be studied to produce longer lasting electronic devices over 30 years. The reliability of the visual prosthesis has not been well studied in any other professional research labs, so this thesis may give or address some initial guidelines to help save time for the project decision in the future to develop advanced hermetic packaging for bioimplantable electronic devices.
Ph.D. in Materials Science and Engineering, July 2011
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- Title
- UNMANNED AIRCRAFT SYSTEM SENSE AND AVOID INTEGRITY AND CONTINUITY
- Creator
- Jamoom, Michael B.
- Date
- 2016, 2016-05
- Description
-
This thesis describes new methods to guarantee safety of sense and avoid (SAA) functions for Unmanned Aircraft Systems (UAS) by evaluating...
Show moreThis thesis describes new methods to guarantee safety of sense and avoid (SAA) functions for Unmanned Aircraft Systems (UAS) by evaluating integrity and continuity risks. Previous SAA e↵orts focused on relative safety metrics, such as risk ratios, comparing the risk of using an SAA system versus not using it. The methods in this thesis evaluate integrity and continuity risks as absolute measures of safety, as is the established practice in commercial aircraft terminal area navigation applications. The main contribution of this thesis is a derivation of a new method, based on a standard intruder relative constant velocity assumption, that uses hazard state estimates and estimate error covariances to establish (1) the integrity risk of the SAA system not detecting imminent loss of “well clear,” which is the time and distance required to maintain safe separation from intruder aircraft, and (2) the probability of false alert, the continuity risk. Another contribution is applying these integrity and continuity risk evaluation methods to set quantifiable and certifiable safety requirements on sensors. A sensitivity analysis uses this methodology to evaluate the impact of sensor errors on integrity and continuity risks. The penultimate contribution is an integrity and continuity risk evaluation where the estimation model is refined to address realistic intruder relative linear accelerations, which goes beyond the current constant velocity standard. The final contribution is an integrity and continuity risk evaluation addressing multiple intruders. This evaluation is a new innovation-based method to determine the risk of mis-associating intruder measurements. A mis-association occurs when the SAA system incorrectly associates a measurement to the wrong intruder, causing large errors in the estimated intruder trajectories. The new methods described in this thesis can help ensure safe encounters between aircraft and enable SAA sensor certification for UAS integration into the National Airspace System.
Ph.D. in Mechanical and Aerospace Engineering, May 2016
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- Title
- UNDERSTANDING DELIBERATIVE AND INTUITIVE DECISION MAKING ABOUT HAZARDS ON CONSTRUCTION SITES
- Creator
- Saxena, Jaya
- Date
- 2013, 2013-12
- Description
-
During the course of performing daily tasks, construction workers encounter numerous hazards, such as ladders that are too short to reach the...
Show moreDuring the course of performing daily tasks, construction workers encounter numerous hazards, such as ladders that are too short to reach the work area, energized electrical lines, or inadequate fall protection. When a hazard is encountered, the worker must make a rapid decision about how to respond and whether to take or avoid the risk. The goal of this researchwas to construct a theory about the influence of decision cues on intuitive and deliberative decision-making in high-hazard construction environments. Drawing from Cognitive Continuum Theory, the study specifies a framework for understanding why and how construction workers make decisions that lead to taking or avoiding physical risks when they encounter daily hazards. A secondary aim of the research was to construct a set of hypotheses about how specific decision cues influence whether a worker is more likely to engage their intuitive impulses or to use careful deliberationwhen responding to a hazard. These hypotheses are described and the efficacy of the hypotheses was evaluated using cross-tabulations and nonparametric measures of association. While most of the associations between decision cues and decision mode (i.e., intuition or deliberation) identified in this data set were generally modest, none of the associations were statistically zero, thus indicating that further research is warranted based on theoretical grounds. The qualitative data set was analysed using Decision Trees and Recognition Primed Decision Models.A rigorous program of theory testing is the next logical step to the research, and the thesis thus concludes with numerous suggestions for extending the research and testing the proposed hypotheses
M.S. in Civil Engineering, December 2013
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- Title
- FPGA IMPLEMENTATION OF ULTRASONIC FLAW DETECTION ALGORITHM BASED ON SUPPORT VECTOR MACHINE CLASSIFICATION
- Creator
- Jiang, Yiyue
- Date
- 2016, 2016-12
- Description
-
In this study, a Support Vector Machine (SVM) classification method used for analyzing Ultrasound signals is implemented by FPGAs based on...
Show moreIn this study, a Support Vector Machine (SVM) classification method used for analyzing Ultrasound signals is implemented by FPGAs based on Xilinx Zynq SoC. The SVM processor aims at classifying A-scan data obtained by an ultrasonic sensor. For reducing development time, hardware software co-design tools such as Xilinx System Generator and Vivado have been used. SVM kernel function is implemented by DSP slices and block RAMs. Advanced Extensible Interface bridges the ARM core and FPGAs for more convenient communication. The main objective of this study is to achieve robust detection of ultrasonic flaw echoes in real-time using an SVM algorithm. The implementation on the FPGA shows that the architecture can be realized with a Xilinx Zedboard FPGA. It runs at 100MHz clock frequency and can calculate the SVM classification for 1024 feature space points under 0.02ms.
M.S. in Electrical Engineering, December 2016
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- Title
- SERVICEABILITY REQUIREMENTS FOR FLOOR SYSTEMS - A REVIEW OF CURRENT STANDARDS AND PRACTICES
- Creator
- Jaafari, Chaimaa
- Date
- 2017, 2017-07
- Description
-
Serviceability requirements are considered in any design to maintain the occupants’ comfort in buildings. Specifically, issues such as floor...
Show moreServiceability requirements are considered in any design to maintain the occupants’ comfort in buildings. Specifically, issues such as floor system deflections and vibrations are two important considerations for design as relate to serviceability. Design codes primarily address the deflection control yet rarely address the vibration. Although the vibration may be related to deflection, maintaining the comfort of occupants will require a detailed study on the level of vibration and its frequency that would be comfortable to the occupants. This research will examine and summarize the serviceability requirements as suggested by various codes and standards and also as suggested by published papers. Specifically, the research focuses on deflection and vibration control for floor systems based on the occupancy and usage and the types of structures and sources of vibrations. Methods to alter existing floor system designs to control vibrations will also be presented. The final research outcome will be a complete document summarizing the findings on what is perceived as good practice for deflection and vibration control for floor system designs in buildings.
M.S. in Civil Engineering, July 2017
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- Title
- ELECTROCATALYSTS FOR ALKALINE WATER ELECTROCATALYSIS
- Creator
- Jain, Anchal
- Date
- 2016, 2016-07
- Description
-
Hydrogen is an attractive energy carrier and is part of an idealistic future wherein it serves as a clean energy source. In the presence of...
Show moreHydrogen is an attractive energy carrier and is part of an idealistic future wherein it serves as a clean energy source. In the presence of oxygen, it can be converted to water in fuel cells with the release of heat and electrical work. Electrolysis of water is an important route to hydrogen generation. Alkaline water electrolysis is preferred over electrolysis in acidic medium due to the possibility of lowering stack costs and enhancing the library of stable electrocatalyst materials available for the electrochemical reactions. The high anode overpotential arising from the sluggish oxygen evolution reaction (OER) has led to significant interest in developing stable and active OER electrocatalysts. IrO2 (state of the art catalyst), RuO2 and PGM-based pyrochlores are suitable catalyst materials that exist today, but there is benefit in finding cost-effective alternatives. In this study, the pyrochlore oxides containing non- Platinum Group Metals (non-PGM) metals were synthesized by solid state reaction and were tested for their OER activity but none of the materials tested, exhibited OER activity and a comparison was attempted between the pyrochlores containing PGM metals as against those containing non-PGM metals. Additionally, perovskite oxides of the form La[Ni(1-x-y)CoxFey]O3 (where 0≤x≤1 and 0≤y≤1) were synthesized by the co-precipitation method. Many of these perovskites exhibited electron conductivities greater than 0.1S/cm, eliminating the need to add carbon for OER studies and implying the likelihood of making conducting electrodes with these materials without the additives like carbon. The perovskites LaNi0.6Co0.4O3 or LaNi0.6Fe0.4O3 with x/y =0.4 had conductivities of the order of 10S/cm. The electrocatalytic activity for the OER was studied using a rotating disk electrode (RDE) in 0.1M KOH and catalyst loading of ~100μg/cm2. The perovskite LaNi0.5Co0.5O3 (x=0.5, y=0) had the onset potential of ~1.50V against RHE, and all these perovskites had onset potentials ~0.1-0.15V higher than the benchmark IrO2 that has an onset potential of ~1.43V. Few of the perovskites were also evaluated for their oxygen reduction activity (ORR) implying that these materials can be used as bi-functional catalysts.
M.S. in Chemical Engineering, July 2016
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- Title
- DYNAMIC ANALYSIS OF UNCERTAIN STRUCTURES USING IMPRECISE PROBABILIY
- Creator
- Bergerson, Joshua D.
- Date
- 2014, 2014-05
- Description
-
A new method for dynamic response spectrum analysis of structures with uncertainty in their mechanical properties utilizing the notion of...
Show moreA new method for dynamic response spectrum analysis of structures with uncertainty in their mechanical properties utilizing the notion of imprecise probability is developed. This finite-element-based method is capable of obtaining probabilistic bounds of the dynamic response of the structure with uncertainty defined by enveloping p-boxes. The developed method obtains probabilistic bounds on 1) the mode shapes, 2) modal coordinates, and 3) modal participation factor, leading to the p-boxes of modal responses. Finally maximum modal responses are combined to obtain the structure’s maximum total response with consideration of uncertainty. Numerical examples demonstrating the developed method are included. Keywords: Structural Dynamics, Uncertainty, Imprecise Probability, P-Box.
PH.D in Civil Engineering, May 2014
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- Title
- FATIGUE, FRACTURE, AND CRACK GROWTH BEHAVIOR OF FIVE CANDIDATE STEELS FOR WIND TOWER APPLICATION
- Creator
- Tsosie, Henrietta R.
- Date
- 2011-08, 2011-07
- Description
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Fatigue, fracture toughness, and crack propagation tests were performed on five candidate steels for wind tower applications. Normally, these...
Show moreFatigue, fracture toughness, and crack propagation tests were performed on five candidate steels for wind tower applications. Normally, these steels are ordered to meet ASTM A572/A709 Grade 50 or EN 10025-2 Grade S355 in the normalized condition. Five steels with varying carbon content and alloy additions focusing on niobium and vanadium content are investigated. Two of the five steels are in the normalized condition to check the EN 10025-2 requirement while the rest are in the as-rolled condition. Fatigue tests were performed to determine the endurance limit using a constant amplitude loading at a constant load ratio. Fracture toughness testing using the J integral method was performed to determine the critical fracture energy, Jc. This value is then converted to the critical plain strain stress intensity factor if requirements are met. Three fracture toughness tests were performed for each material at room temperature using a C(T) specimen. Crack propagation tests were performed to determine the Paris constants using a contoured double cantilever beam specimen. The steels with niobium give better results in fatigue and displayed smaller grain diameters than the steels with vanadium. The fatigue results for the low carbon steel with niobium are comparable to another HPS steel. Overall, the low carbon steel with niobium provides better toughness, fatigue resistance, and weldability than the steels that are normalized to meet the EN 10025-2 requirement for wind tower plates.
M.S. in Materials Science and Engineering, July 2011
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- Title
- SCALABLE INDEXING AND SEARCHING ON DISTRIBUTED FILE SYSTEMS
- Creator
- Ijagbone, Itua
- Date
- 2016, 2016-05
- Description
-
Scientific applications and other High Performance applications generate large amounts of data. It’s said that unstructured data comprises...
Show moreScientific applications and other High Performance applications generate large amounts of data. It’s said that unstructured data comprises more than 90% of the world’s information [IDC2011], and it’s growing 60% annually [Grantz2008]. The large amounts of data generated from computation leads to data been dispersed over the file system. Problems begin to exist when we need to locate these files for later use. For small amount of files this might not be an issue but as the number of files begin to grow as well as the increase in size of these files, it becomes difficult locating these files on the file system using ordinary methods like GNU Grep [8], which is commonly used in High Performance Computing and Many-Task Computing environments. It is as a result of this problem that we have chosen this thesis to tackle the problem of finding files in a distributed system environment. Our work leverages the FusionFS [1] distributed file system and the Apache Lucene [10] centralized indexing engine as a fundamental building block. We designed and implemented a distributed search interface within the FusionFS file system that makes both indexing and searching the index across a distributed system simple. We have evaluated our system up to 64 nodes, compared it with Grep, Hadoop, and Cloudera, and have shown that FusionFS’s indexing capabilities have lower overheads and faster response times.
M.S. in Computer Science, May 2016
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- Title
- SIMILAR VOICES, SAME PERSPECTIVES? INTERNATIONAL MOVIE REVIEWERS AT THE IMDB
- Creator
- Gao, Jing
- Date
- 2012-04-21, 2012-05
- Description
-
Online communities enable people from around the world to interact online. But having the opportunity to speak and being heard are two...
Show moreOnline communities enable people from around the world to interact online. But having the opportunity to speak and being heard are two different issues. In most cases of intercultural communication online, people from different cultures interact in English. Are they still able to bring their own perspectives without using their native language? This study thus focuses on whether or not international voices are heard online and whether or not these voices that find audiences are really differ- ent, as compared to the local voice (i.e., dominant or majority voice). We question whether or not international voices are different, as previous studies on intercultural communication debate over whether or not voices are different by culture. Results of a content analysis show that international and U.S. participants tend to contribute similar content, which contrasts with the common assumption that people from dif- ferent cultures will write differently and resonates with previous studies that have proposed that culture, on its own, is not an effective predictor of online behavior.
M.S. in Technical Communication and Information Design, May 2012
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- Title
- INVESTIGATION OF PERFORMANCE AND DURABILITY OF POLYMER ELECTROLYTES FOR ELECTROCHEMICAL ENERGY STORAGE AND CONVERSION TECHNOLOGIES
- Creator
- Jung, Min-suk
- Date
- 2016, 2016-07
- Description
-
Polymeric ion exchange membranes are integral components of electrochemical conversion/storage devices such as fuel cells, water electrolyzers...
Show morePolymeric ion exchange membranes are integral components of electrochemical conversion/storage devices such as fuel cells, water electrolyzers, and redox flow batteries. There has been dramatic progress in the research and development of cation exchange membranes (CEM). Nafion® (perfluorosulfonic acid membranes) is one example of a state-of-the-art CEM and has been successfully demonstrated in various electrochemical energy devices. Unlike CEMs, anion exchange membranes (AEMs) have been of limited utility to date due to their drawbacks, including poor chemical/mechanical stability and low ionic conductivity. However, alkaline environments result in better activity for electrochemical reactions and afford the possibility of using non-platinum group metal (PGM) electrocatalysts. AEMs, therefore, are still being studied in order to resolve existing challenges in terms of conductivity and stability in alkaline media and in strongly oxidizing solutions. In this work, AEMs derived from different types of polymer backbones were prepared, and their chemical stability and electrochemical property were investigated. Polysulfone (PSF) AEMs were prepared by first chloromethylating polysulfone, then by functionalizing chloromethylated polysulfone (CMPSF) with different base reagents. PSF-trimethylamine (TMA) AEMs showed a 40-fold reduction in vanadium (IV) ion (VO2+) permeability when compared to a Nafion® membrane and exceptional oxidative stability after exposure to a 1.5 M vanadium (V) ion (VO2 +) solution for 90 days. PSF-TMA AEMs were successfully demonstrated in the all-vanadium redox flow battery. Excellent energy efficiencies (>75 %) were attained and sustained over 75 chargedischarge cycles for a vanadium redox flow battery prepared using the PSF-TMA separator. Crosslinking of poly(2,6-dimethyl-1,4-phenylene oxide) (PPO) AEMs using diamine was tried with intentions to improve the mechanical stability and electrochemical property of PPO AEM. Crosslinked PPO AEMs (30 ± 4 % at 25 oC) showed less liquid water uptake than non-crosslinked PPO AEMs (46 ± 5% at 25 oC) while maintaining comparable ionic conductivities (hydroxide ion conductivity of 45 mS/cm at 60 oC). Crosslinked PPO AEMs maintained mechanical integrity and still showed some mechanical stability (ultimate tensile strength of 3~4 MPa and elongation at break of 13~17 %) after exposure to 1 M KOH at 60 oC for 14 days, while noncrosslinked PPO AEMs completely lost their mechanical durability. Finally, this dissertation presents research related to perfluorinated AEMs prepared using a Grignard reagent. These membranes exhibited 0.7 mmol/g of Cl- ion exchange capacity (IEC), 20 mS/cm of hydroxide ion conductivity at 20 oC, and 10 % of water uptake at room temperature. The membranes also maintained 90 % of their initial conductivity after an exposure to 1.5 M VO2+ in 3 M H2SO4 solution for seven days.
Ph.D. in Chemical Engineering, July 2016
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- Title
- DEVELOPING INTELLIGENT AND ADAPTIVE BUILDING SYSTEMS FOR OUR DIGITAL ECOLOGY
- Creator
- Hansen, Kai
- Date
- 2013, 2013-07
- Description
-
Our world is being changed by a dynamic digital presence. The marriage of virtual and physical represents an ecology which has become...
Show moreOur world is being changed by a dynamic digital presence. The marriage of virtual and physical represents an ecology which has become intertwined with the lives of nearly everyone, fundamentally altering how our society functions. While we have evolved in this sense, the built environment has become outmoded and strains to meet emerging occupant requirements. To correct this, it has become necessary to develop environments that are capable of intelligently responding to shifting requirements. As curators of the built environment, architects are responsible for seeking out and engaging new mechanisms to achieve spaces that occupants find desirable. An experiential summary of the architectural-digital-hacking process will be given. A more traditional research method was followed when possible while engaged in this learning process. This research focuses on utilizing readily available digital tools that are capable of simultaneously mitigating issues associated with occupant requirements and energy consumption. It will also address shortcomings related to occupant comfort and energy consumption observed in our buildings by producing a series of working prototypes that will be tested and analyzed. Results will be presented, and will consist of components used and how they were used to serve as a reference for future development.
M.S. in Architecture, July 2013
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- Title
- Sensemaking for Power Asymmetries in Anti-Oppressive Design Practice
- Creator
- Meharry, Jessica J
- Date
- 2022
- Description
-
Within professional design practice in capitalist market contexts, the goals of user-centered and human-centered design methodologies is to...
Show moreWithin professional design practice in capitalist market contexts, the goals of user-centered and human-centered design methodologies is to make algorithmically-based technologies understandable for users, satisfy customer needs and desires, and thereby increase corporate profitability. However, there is growing concern that the computational methods, data management, and business models that drive these technologies are leading to global asymmetries of knowledge, information, and power. The asymmetries of power generated by these designed interactions can be considered the kind of wicked problem that design seeks to address. Yet the dominant goals and methods of professional design practice limit their ability to design ethically within market contexts. These methodologies fail to adequately consider systemic context and power relations, potential for bias in algorithmic computation, and specific forms of systemic oppression. These gaps then lead to inadequate design solutions. This study explores these gaps in design methodologies that could be transferable to a range of professional (and non-professional) practices by looking at potential new levers within familiar design methods and their effectiveness as facilitating problem reframing towards equitable solutions. This dissertation advances knowledge in design by exploring how professional designers can better understand how to use sensemaking processes for salience of power asymmetries, algorithmic materiality, and systemic oppression. It proposes an anti-oppressive design framework that is rooted in a critically-informed design praxis. These orientations rethink and recreate design knowledge by helping professional designers shift the market-focused paradigm for which they are designing.
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- Title
- Non-Hermitian Phononics
- Creator
- Mokhtari, Amir Ashkan
- Date
- 2021
- Description
-
Non-Hermitian and open systems are those that interact with their environment by the flows of energy, particles, and information. These systems...
Show moreNon-Hermitian and open systems are those that interact with their environment by the flows of energy, particles, and information. These systems show rich physical behaviors such as unidirectional wave reflection, enhanced transmission, and enhanced sensitivity to external perturbations comparing to a Hermitian system. To study non-Hermitian and open systems, we first present key concepts and required mathematical tools such as the theory of linear operators, linear algebra, biorthogonality, and exceptional points. We first consider the operator properties of various phononic eigenvalue problems. The aim is to answer some fundamental questions about the eigenvalues and eigenvectors of phononic operators. These include questions about the potential real and complex nature of the eigenvalues, whether the eigenvectors form a complete basis, what are the right orthogonality relationships, and how to create a complete basis when none may exist at the outset. In doing so we present a unified understanding of the properties of the phononic eigenvalues and eigenvectors which would emerge from any numerical method employed to compute such quantities. Next, we apply the mentioned theories on the phononic operators to the problem of scattering of in-plane waves at an interface between a homogeneous medium and a layered composite. This problem is an example of a non self-adjoint operator with biorthogonal eigenvectors and a complex spectrum. Since this problem is non self-adjoint, the degeneracies in the spectrum generally represent a coalescing of both the eigenvalues and eigenvectors (exceptional points). These degeneracies appear in both the complex and real domains of the wavevector. After calculating the eigenvalues and eigenvectors, we then calculate the scattered fields through a novel application of the Betti-Rayleigh reciprocity theorem. Several numerical examples showing rich scattering phenomena are presented afterward. We also prove that energy flux conservation is a restatement of the biorthogonality relationship of the non self-adjoint operators. Finally, we discuss open elastodynamics as a subset of non-Hermitian systems. A basic concept in open systems is effective Hamiltonian. It is a Hamiltonian that acts in the space of reduced set of degrees of freedom in a system and describes only a part of the eigenvalue spectrum of the total Hamiltonian. We present the Feshbach projection operator formalism -- traditionally used for calculating effective Hamiltonians of subsystems in quantum systems -- in the context of mechanical wave propagation problems. The formalism allows for the direct formal representation of effective Hamiltonians of finite systems which are interacting with their environment. This results in a smaller set of equations which isolate the dynamics of the system from the rest of the larger problem that is usually infinite size. We then present the procedure to calculate the Green's function of effective Hamiltonian. Finally we solve the scattering problem in 1D discrete systems using the Green's function method.
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- Title
- AN EXPLORATION INTO THE EFFECTS OF CHROMATIN STRUCTURAL PROTEINS ON THE DYNAMICS AND ENERGETIC LANDSCAPE OF NUCLEOSOME ARCHITECTURES
- Creator
- Woods, Dustin C
- Date
- 2022
- Description
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Comprised of eight core histones wrapped around at least 147 base pairs of DNA, nucleosomes are the fundamental unit the chromatin fiber from...
Show moreComprised of eight core histones wrapped around at least 147 base pairs of DNA, nucleosomes are the fundamental unit the chromatin fiber from which long arrays are built to compact genetic information into the cell nucleus. Structural proteins, such as linker histones (LH) and centromere proteins (CENP), interact with the DNA to dictate the exact architecture of the fiber which can directly influence the regulation of epigentic processes. However, the mechanisms by which structural proteins affect these processes are poorly understood. In this thesis, I will explore the various way in which LHs and CENP-N affect nucleosome and, by extension, chromatin fiber dynamics. First, I present a series of simulations of nucleosomes bound to LHs, otherwise known as chromatosomes, with the globular domain of two LH variants, generic H1 (genGH1) and H1.0 (GH1.0), to determine how their differences influence chromatosome structures, energetics and dynamics. These simulations highlight the thermodynamic basis for different LH binding motifs, and details their physical and chemical effects on chromatosomes. Second, I examine how well the findings above translate from mono-nucleosomes to poly-nucleosome arrays. I present a series of molecular dynamics simulations of octa-nucleosome arrays, based on a cryo-EMstructure of the 30-nm chromatin fiber, with and without the globular domains of the H1 LH to determine how they influence fiber structures and dynamics. These simulations highlight the effects of LH binding on the internal dynamics and global structure of poly- nucleosome arrays, while providing physical insight into a mechanism of chromatin compaction. Third, I took a brief departure from LHs to study the effects that the centromere protein N (CENP-N) has on the poly-nucleosome systems. I present a series of molecular dynamics simulations of CENP-N and di-nucleosome complexes based on cryo- EM and crystal structures provided by Keda Zhou and Karolin Luger. Simulations were conducted with nucleosomes in complex with one, two, and no CENP-Ns. This work, in collaboration with the Karolin Luger Group (University of Colorado – Boulder) and the Aaron Straight Group (Stanford University), represents the first atomistic simulations of this novel complex, providing the foundation for a plethora of future research opportunities exploring centromeric chromatin the effect that its structure and dynamics have on epigenetics. Lastly, I return to the chromatosome to study how DNA sequence affects the free energy surface and detailed mechanism of LH transitions between binding modes. I used umbrella sampling simulations to produce PMFs of chromatosomes wrapped in three different DNA sequences: Widom 601, poly-AT, and poly-CG. This work, my final in the series, represents a culmination of my studies furthering the understanding of biophysical phenomena surrounding LHs and how they can be extrapolated towards epigentic mechanisms. I was able to report on the first PMFs illustrating a previously unknown transition and describe the transition mechanism as it depends on DNA sequence.
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- Title
- Towards Understanding the Microstructure and Mechanical Properties of Additively Manufactured Ni-base Superalloys
- Creator
- Tiparti, Dhruv Reddy
- Date
- 2022
- Description
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Nickel-base superalloy components such as turbine discs typically undergo numerous manufacturing steps that contribute to increasing the cost...
Show moreNickel-base superalloy components such as turbine discs typically undergo numerous manufacturing steps that contribute to increasing the cost and the waste of excess materials. With advent of fusion based additive of manufacturing (AM) techniques, such components with complex geometry can be fabricated with great efficiency. However due to characteristically high energy densities, fast cooling rate, and layer-by-layer building process associated with AM; Ni-base superalloys with higher temperature performance are difficult to be fabricated by AM due to susceptibility to composition related defect formation, which is further exacerbated by anisotropic grain structures induced by the large thermal gradients present. Crack-free material can be fabricated but, in most cases, issues such as an anisotropic microstructure will prevail, and the balance of mechanical properties achieved may not be suitable for the desired applications. Several strategies exist to mitigate the challenges posed by additive manufacturing via post-processing such as hot-isostatic processing, annealing heat treatments, application of grain refining inoculants, etc. All these strategies utilized to mitigate issues with AM of Ni-base superalloys still require further study to understand their effects on the microstructure and mechanical properties. This work aims to evaluate the use of inoculant particles, and novel heat treatments on the microstructure and mechanical properties of different superalloys. First, the effect of varying amounts of CoAl2O4 inoculant ranging from 0 to 2 wt.% on the microstructure evolution of Inconel 718(IN718) fabricated by selective laser melting (SLM) was evaluated. The findings from this study indicated that additions of CoAl2O4 only resulted in a minor degree of grain refinement with slight increase in anisotropy; in addition, a CoAl2O4 ¬content above 0.2 wt.% resulted in the formation of agglomerate inclusions; and that to effectively utilize CoAl2O4 as a grain refining inoculant, process parameters must be further optimized while considering the formation of agglomerates, and other defects. Second, the application of CoAl2¬O4 was extended towards the Direct Energy Deposition (DED) of IN718. Here findings indicated that due to the modification of the thermophysical properties of the melt pool by oxide addition, an earlier onset of large columnar extending across multiple layers occurred while counteracting conditions required for equiaxed grain formation; and these CoAl2O4 were also found to exhibit a potent Zenner pinning effect that maintained the as-built grain structure despite application of extreme high treatment condition of 1200oC for 4 hrs. Third, the tensile and fatigue properties of the DED IN718 with CoAl2O4 were evaluated. Here, it was found that the addition of CoAl2O4 leads to a minor increase in tensile strength in the as-built condition attributed primarily to the fine oxide dispersion; a more modest increase in tensile strength in the heat-treated condition due to grain refinement induced by retaining the as-built grain structure; and that despite the increase in tensile strength with CoAl2O4 a corresponding increase in fatigue life did not occur. Lastly, the processing of René 65 conducted by laser-powder bed fusion(L-PBF) was done and compared to the conventionally cast and wrought material. Here, the effect of the difference in processing route in conjunction with heat treatments was evaluated to understand the creep and stress relaxation behavior. It was found that L-PBF of René 65 led to an overall improved resistance to deformation by creep and relaxation mechanism.
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- Title
- The Studio Practice for Sustainable (Craft) Production
- Creator
- Werdhaningsih, Hendriana
- Date
- 2022
- Description
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Craft market demand globally is rising. On the other hand, the domination of economic goals in craft production is threading the social system...
Show moreCraft market demand globally is rising. On the other hand, the domination of economic goals in craft production is threading the social system and the environment. Craft production facts do not represent the sustainable development principles that should be a central concept for this age. Design as practice and method had not yet correctly facilitated craft production to embrace the harmony of the social, environmental, and economic systems. Believing that studio is a core design practice, this research investigated studio practice through interviews, field research, and action research conducted in Indonesia and the US. It developed a model called Studio Practice for Sustainable (Craft) Production, the SP2 Model. The Model helps designers, the crafts community, and stakeholders ensure their role in the studio practice and determine their goals for sustainable development. The SP2 Model offers alternative practical solutions in craft production, contributes to polycentric discourse, and designs interventions in sustainable development models.
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