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(1 - 5 of 5)
- Title
- ESTIMATES OF FINE AND ULTRAFINE PARTICLE REMOVAL EFFICIENCY FOR RESIDENTIAL HVAC FILTERS USING IN-SITU SIZE-RESOLVED EFFICIENCY MEASUREMENTS
- Creator
- Zeng, Yicheng
- Date
- 2018
- Description
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Central heating, ventilating, and air-conditioning (HVAC) filters are commonly evaluated for their size-resolved particle removal efficiency ...
Show moreCentral heating, ventilating, and air-conditioning (HVAC) filters are commonly evaluated for their size-resolved particle removal efficiency (for particles 0.3 to 10 µm in diameter) by challenging them with a test aerosol in a laboratory setting. However, aerosol measurement and reporting classifications that are most commonly used in regulatory monitoring and building measurements include integral measures of mass-based concentrations (e.g., PM2.5, or the mass concentration of particles smaller than 2.5 µm) or total number concentrations (e.g., total UFPs, or ultrafine particles smaller than 100 nm). Because filter test standards have not traditionally considered these measures, building owners, occupants, and other key personnel cannot make informed decisions on HVAC filtration for these classifications. Moreover, because the removal efficiency for integral measures of total mass and number concentrations are also a function of the underlying particle size distributions that challenge the filter, one must consider the varied sources and size distributions of aerosols that filters encounter in real building applications. This work has two objectives: (1) to measure the in-situ size-resolved particle removal efficiency of a large number of commercially available residential HVAC filters, and (2) to use those size-resolved efficiency data to estimate integral measures of PM2.5 and total UFP removal efficiency for the same filters for typical residential indoor settings based on a literature survey of measured indoor particle size distributions. Particle concentration measurements were made upstream and downstream of a wide range of commercially available filters installed in a central air handling unit in an unoccupied residential apartment unit. A literature review was conducted to gather a variety of indoor particle size distributions (PSDs) from across the world and tri-modal lognormal distributions were fit to each of them. Finally, the particle removal efficiency for each filter for integral measures of indoor UFPs and PM2.5 were calculated for each indoor PSD. In-situ size-resolved measurements indicate that filters with similar rating values but from different manufacturers can have very different removal efficiencies for integral measures of PM2.5 and total UFPs, and that the assumption for indoor PSDs can greatly impact estimates of removal efficiency.
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- Title
- The Effect of Time Step on HSPF Model Performance
- Creator
- Rubinstein, Benjamin J.
- Date
- 2023
- Description
-
Hydrological modeling is a mature and well researched field; however, because most climate data are collected on hour or greater time...
Show moreHydrological modeling is a mature and well researched field; however, because most climate data are collected on hour or greater time intervals there is very little research on the effect of using high resolution data as inputs for the models. A Python tool for downloading high resolution five minute interval data from the Oklahoma Mesonet was created and the PyHSPF Python package was used to generate, calibrate, and validate HSPF models using five minute, one hour, and daily time steps. Flow errors, R², and Nash-Sutcliffe efficiency for simulated outflows, and resource usage were compared for each model. The hourly and five minute models performed similarly well, and the daily model performed significantly worse. The results of this work could prove useful for policy makers and researchers looking to update or create new climate data collection protocols, and the tools used can be applied to many different kinds of future research.
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- Title
- ESTIMATES OF AIR EXCHANGE RATES THROUGH THE USE OF TOTAL VOLATILE ORGANIC COMPOUND DECAY MEASUREMENTS
- Creator
- Bradley, Christopher
- Date
- 2021
- Description
-
Indoor air exchange rates are commonly used to assess the overall fitness of a building and assess its performance. More recently, air...
Show moreIndoor air exchange rates are commonly used to assess the overall fitness of a building and assess its performance. More recently, air exchange has become a concern due to the COVD-19 pandemic, requiring replacement air to ensure safety; especially so considering that humans spend much of their time indoors. Building science has focused on air exchange to quantify needs for thermal loads, balancing the overall tightness of a building with the amount of energy consumed. Moreover, guidelines have been created by several different organizations to maintain adequate ventilation to remove indoor air pollution, replacing it with clean outdoor air. Research focuses on how to maintain a comfortable and safe quality of indoor air while balancing the needs of the energy crisis.When installed with proper HVAC systems, air exchange rates can be set to a recommended value based upon the conditions of the environment. Buildings without mechanical ventilation face another issue, mainly that they only rely on natural ventilation and the infiltration rate. Temperature differences between the indoor and outdoor environment and the condition of wind speed and direction create pressure differences across the building envelope, influencing the infiltration rate, which can change the amount of air exchange in buildings with natural or mechanical ventilation. Currently, air exchange rates are commonly measured using tracer gases. More frequently used gases have included perfluorocarbon, sulfur hexafluoride, and carbon dioxide, though none of these have proven to be ideal tracers. Alongside this, cost and burden on the participants of these studies often limit the amount of measurements made. Numerous studies have been conducted on how to model the air exchange rate by the changes in concentrations, but accuracy depends on the amount of information available. Other attempts have been made to characterize buildings by their infiltration rate to make estimations, but other questions have arisen about the accuracy of these methods. Due to their ubiquity in indoor environments, volatile organic compounds have been suggested as a plausible tracer gas for measuring air exchange rates. The plausibility of this method raises questions, such as their behavior within the indoor environment, their ability to be measured and the cost to measure concentrations, and the analytical requirements to characterize the rates of removal as air exchange rates. However, due to the rapid increase of available technology in low cost, lightweight, high-resolution sensors, this novel method of using VOCs, especially indicators of total VOCs (TVOCs), may prove fruitful in measuring air exchange within specific microenvironments. Analysis of time-series TVOC concentration measurements taken from a study conducted in multiple residences was conducted to investigate the feasibility of using these measurements, and especially naturally occurring elevation and decay periods, as a proxy for calculating air exchange rates. Though the removal rates of these compounds fell within the range of typical air exchange rates for residential spaces, the results of this analysis suggest the method has potential but with limitations, including the unknown behavior of the individual compounds comprising TVOC measurements within the space, proximity and mixing effects, and potentially invalid comparisons to air exchange rates given from a LBLX model rather than simultaneous tracer gas tests. Future work should explore simultaneous use of TVOC measurements alongside conventional tracer gas testing to further explore the potential utility of such methods.
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- Title
- PER – AND POLYFLUOROALKYL SUBSTANCES FATE AND TRANSPORT IN SEDIMENTS, SAND, AND ADSORBENT MEDIA
- Creator
- Manwatkar, Prashik
- Date
- 2022
- Description
-
Perfluorooctanoic acid (PFOA) and perfluorooctane sulfonate (PFOS) are two important organic chemicals of the per- and polyfuoroalkyl...
Show morePerfluorooctanoic acid (PFOA) and perfluorooctane sulfonate (PFOS) are two important organic chemicals of the per- and polyfuoroalkyl substances (PFAS) group that have contaminated land, water, and the air since 1950. The continuous release of PFAS from the surface of land into water is not easy to forecast and an appropriate treatment method needs to be economically viable since there are currently around 42,000 suspect industrial and municipal sites in the United States. For a true reproduction of real-world pollution patterns, we constructed polypropylene tanks, performed laboratory-based experiments, and analyzed the samples using EPA method 533. In this study, we examined the fate and transport of long- and short-chain PFAS, including PFOA, PFOS, and perfluorobutanesulfonic acid (PFBS), from sediments, adsorbent media, and sands under overlaying water tanks. Granular activated carbon (GAC), biochar (BC), and Fluorosorb® (FS) were also added between the contaminated sediments and the sand layer in order to observe capping effectiveness. As one of the best ways to treat contaminated sediments on a large scale, adsorbent beds may reduce contaminants migration and support the degradation of contaminants. We found that all three chemicals were able to pass through the adsorbent layers of 3-4 inches from 4-5 inches of contaminated sediments and reach the top surface of the beds (25-30 inches). In the top 5-7 inches, PFBS concentration varied from 0.28 ppb to 0.78 ppb for all adsorbent tanks for 7 days. Whereas the bottom contaminated sediments concentrations of PFBS were 8518 ppb to 9481 ppb. We also observed the concentrations at top ports increased by 0.59 ppb to 2.31 ppb in 21 days, and ultimately, 0.58 ppb to 7.07 ppb in 69 days. While PFOA and PFOS found different metabolites in all layers, they provided noticeably lesser concentrations in contaminated sediments compared to PFBS. Further, the results of this study can be useful for validating the contaminant transport model predictions by identifying linear or nonlinear sorption equilibrium processes and diffusion-dispersion processes in sediment, sand, and various adsorbent media.
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- Title
- High-latitude plasma drift structuring from a first principles ionospheric model
- Creator
- Kim, Heejin
- Date
- 2020
- Description
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In the high-latitude ionosphere dense plasma formations called polar cap patches are sometimes observed. These patches are often associated...
Show moreIn the high-latitude ionosphere dense plasma formations called polar cap patches are sometimes observed. These patches are often associated with ionospheric scintillation, a rapid fluctuation in the amplitude and phase of a radio signal that degrades communications and navigation systems. Predicting polar cap patch movement across the polar cap is an important subject for enabling forecasting of the scintillation.Lagrangian coherent structures (LCSs) are ridges indicating regions of maximum fluid separation in a time-varying flow. In previous studies, the Ionosphere-Thermosphere Algorithm for Lagrangian Coherent Structures (ITALCS) predicted the location of LCSs. These LCSs were shown to constrain polar cap patch source and transport regions for flow assumed to due to $\vec{E} \times \vec{B}$ plasma drift. The LCSs were predicted based on an empirical model of the high-latitude electric field for $\vec{E}$. In this thesis, the LCSs are generated using the first principles ionospheric model SAMI3 (SAMI3 is Another Model of the Ionosphere) as the model for electric field. The work relies on an understanding of various magnetic coordinate systems in space science, and includes three different approaches for attempting to generate the $\vec{E} \times \vec{B}$ drift as the flow fields that are to input to ITALCS. Finally, a representative LCS result is obtained with SAMI3 and shown to be at the high latitudes on the dayside, similar to prior work, but spanning a shorter longitudinal range.
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