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- Title
- UNDERSTANDING THE FUNDAMENTAL MECHANISMS OF MESO-SCALE ENGINEERING OF GRAIN BOUNDARIES IN NI-BASE SUPERALLOYS
- Creator
- Alabbad, Bader
- Date
- 2019
- Description
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Polycrystalline nickel base superalloys are known to possess high temperature strength, good crack growth resistance and corrosion resistance...
Show morePolycrystalline nickel base superalloys are known to possess high temperature strength, good crack growth resistance and corrosion resistance at high temperatures. Engineering the morphology of the grain boundaries can yield to extent the high temperature resistance for polycrystalline nickel-based superalloys. Meso-scale engineering for grain boundary structures can be utilized through the development of serrated grain boundaries to improve the damage tolerance of polycrystalline nickel- based superalloys. Grain boundary precipitates induce the formation of the grain boundary serrations as precipitates protrude the grain boundary. Understanding and controlling the cooling processes from above the solvus temperature plays an important role in controlling the size and population of γ′ precipitates to modify specific microstructural features that can impact the resulting properties. Two stepped cooling process with a transition just below the γ′ solvus has the ability to form a unique microstructure as heterogeneous nucleation and growth of large γ′ precipitates along the grain boundaries during the initially slow cooling rate. The eventual transition to a standard or conventional cooling rate will then govern the formation of the secondary, intragranular γ′ precipitates. The stepped cooling process was compared to the conventional fast continuous cooling process. The effect of grain boundary misorientation on the precipitation behavior of grain boundary γ′ precipitates revealed coarse grain boundary γ′ precipitates reside along high angle grain boundaries. Mechanical testing was carried out to investigate their mechanical properties to compare and benchmark to those produced via conventional continuous cooling to quantify the extent by which serrated boundaries can be used to improve the properties where the modified microstructures led to great high temperature properties.Nickel-base superalloy 718Plus is a recently developed alloy that is being considered for use in a number of advanced gas turbine engine applications. A constructed heat treatment was proposed to drive the precipitation of fine η precipitates along grain boundaries. Lamellar η phase precipitates were able to induce the formation of serrated grain boundaries. Discontinuous cellular precipitation reaction led the formation of the lamellar η phase precipitates. The characteristic growth of lamellar η phase precipitates was influence by the grain boundary structure. Creep tests were carried out to provide a better understanding of how serrated grain boundaries formed using η phase precipitates can impact the creep properties of ATI 718Plus.
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- Title
- SYNTHESIS OF HIGH PERFORMANCE SILICON ANODES AND SURFACE-MODIFIED NMC CATHODES FOR LI-ION BATTERIES
- Creator
- Ashuri, Maziar
- Date
- 2019
- Description
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Lithium-ion batteries (LIBs) have revolutionized the portable electronic devices and electric vehicles (EV) and because of this huge demand,...
Show moreLithium-ion batteries (LIBs) have revolutionized the portable electronic devices and electric vehicles (EV) and because of this huge demand, it is important to meet high power, high specific energy, and long cycle life. All mentioned characteristics are directly related to the choice of anode and cathode electrodes. Currently, graphite is used as anode, while lithium cobalt oxide serves as cathode dominantly. Although graphite can deliver ~ 370 mA h g-1 capacity without significant capacity decay for several cycles, however it is not enough to fulfill the requirements for many applications. Silicon with the theoretical capacity of about 10 times higher than graphite is a promising anode. However, this material suffers from huge volume expansion during cycling in addition to its intrinsic low conductivity. From the cathode viewpoint, the need for materials with less cobalt content is necessary. The resources for cobalt element is very limited while the price of cobalt increasing. Furthermore, cobalt is known as toxic element. Therefore, substitution of cobalt with other elements such as manganese and nickel is necessary. Lithium nickel manganese cobalt oxide (NMC) cathode family materials are introduced following this idea.Here in this thesis, two different approaches are introduced to harness the problems associated with silicon anodes. The first approach is the core/shell design and the second one is the silicon/graphite nanocomposite with tailored structure and engineered voids. Both of these designs can be synthesized easily without complicatedsynthesis steps and harmful chemicals. They have the potential of being commercialized and they do not need expensive equipment. The silicon anodes have been tested successfully in the half-cell coin cells.As for the cathode side, two different members of NMC family materials (NMC333 and NMC532) have been tested. To enhance their electrochemical properties and rate capabilities, a facile surface modification using phosphoric acid was employed. This technique resulted in the formation of thin lithium phosphate coating around the particle. The electrodes performed very well in half-cell configuration. It is expected by utilizing the proposed cathode and anode materials in full-cell set up, a high performance battery with fast charge ability is obtained.
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- Title
- Superior Reversible Hydrogen Storage of the LiBH4 + MgH2 System Enabled by High-Energy Ball Milling with In-Situ Aerosol Spraying
- Creator
- Ding, Zhao
- Date
- 2019
- Description
-
The prospect of LiBH4 + MgH2 mixture has been limited by its sluggish kinetics, despite its excellent hydrogen storage capacity theoretically....
Show moreThe prospect of LiBH4 + MgH2 mixture has been limited by its sluggish kinetics, despite its excellent hydrogen storage capacity theoretically. We have designed a novel process termed as high-energy ball milling of MgH2 at ambient temperature along with aerosol spraying of LiBH4 dissolved in tetrahydrofuran (THF) solution (BMAS) to improve the thermodynamic and kinetic performance of LiBH4 + MgH2 hydrogen storage materials. Through this BMAS process, we have demonstrated that, for the first time, the reaction between LiBH4 + MgH2 can take place near ambient temperature, and the in-situ formation of LiH and MgB2 during BMAS is achieved through a new reaction pathway in which nano-LiBH4 decomposes to Li2B12H12 first and the newly formed Li2B12H12 reacts with MgH2 to form LiH and MgB2.Using the newly designed automated BMAS apparatus, we have successfully produced a BMAS mixture containing 1 mole of MgH2 + 0.5 mole of LiBH4, i.e., with 25% LiBH4 in the mixture for the stoichiometric reaction. The BMAS powder with 25% LiBH4 can release and absorb ~5.7 wt.% H2 at 265 oC, which is the highest one ever reported for the LiBH4 + MgH2 system at temperature ≤ 265 oC. It is found that the unusually high reversible hydrogen storage is accomplished through two parallel reaction pathways. One is nano-LiBH4 decomposes to form Li2B12H12 and H2 first and then Li2B12H12 reacts with MgH2 to form MgB2, LiH and H2. The other is nano-MgH2 decomposes to form Mg and H2 first and then Mg reacts with LiBH4 to form MgB2, LiH and H2. These reaction pathways become possible because of the presence of nano-LiBH4 and nano-MgH2 and their intimate mixing, enabled by the BMAS process. We have also revealed that the solid-state dehydrogenation kinetics of the BMAS powder with 25% LiBH4 at 265 oC is nucleation-and-growth controlled. The rate-limiting step for dehydrogenation via the two parallel reaction pathways has been identified through examination of the elementary reactions as the nucleation and growth of reaction products LiH and MgB2. Given the significantly improved hydrogen storage capacity for the LiBH4 + MgH2 system obtained via BMAS, investigation on increasing the LiBH4 content in the BMAS powder from 25% to 50% is performed. It is shown that Mg(BH4)2 can be produced during the BMAS process and it contributes to H2 release at temperature ≤ 265 oC. Three parallel H2 release mechanisms have been identified from the BMAS powder. These include (i) nano-LiBH4 decomposes to form Li2B12H12 and H2 first and then Li2B12H12 reacts with MgH2 to form MgB2, LiH and H2, (ii) nano-Mg(BH4)2 decomposes to form MgH2, B and H2, and (iii) nano-MgH2 decomposes to Mg and H2. Together these three mechanisms result in 4.11 wt.% H2 release in the solid state at temperature ≤ 265 oC. Furthermore, the predicted property of Fe3B in absorbing more H2 than releasing it is confirmed experimentally for the first time in this study. Varied models have been identified to describe the kinetic of solid-state dehydrogenation of the BMAS powder with 50% LiBH4 at 265 oC with increasing cycles. Additionally, the geometries of the solid particles involving with the dehydrogenation have also been estimated.
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- Title
- Structural Studies of Degradation Mechanism of Lithium Rich Manganese, Nickel, and Iron Based Cathodes
- Creator
- Aryal, Shankar
- Date
- 2018
- Description
-
Layered oxide compounds are superior with respect to discharge voltage and discharge specific capacity compared to other families of cathodes....
Show moreLayered oxide compounds are superior with respect to discharge voltage and discharge specific capacity compared to other families of cathodes. Therefore, LiCoO2 and LiMnxNiyCozO2, are the most commonly used cathodes since the commercialization of lithium ion battery. Recently, Li rich Ni, Mn, and Co oxide composite cathodes have been introduced with some improvements. As Co is toxic and expensive, attempts have been made to replace Co with cheap and environmentally friendly Fe. This dissertation reports that comparable discharge specific capacity and discharge voltage can be achieved by replacing Co with Fe and optimizing the composition of Mn, Ni, and Fe. However, the capacity and voltage fading on cycling are still remaining challenges. Structural change on electrochemical cycling is the main reason behind this fading. X-ray absorption spectroscopy (XAS), the specific element probe technique to study local structure and X-ray diffraction (XRD) to study the crystallographic phase information are utilized to understand the degradation/aging mechanism. A series of Li rich Mn, Ni, and Fe oxide composite cathode materials Li1.2Mn(0.30+x)Ni(0.40-x)Fe0.10O2 for x = 0, 0.05, 0.10, 0.15, 0.20 and 0.25 were prepared using a sol-gel synthesis method. Rhombohedral and monoclinic crystal phases are found in Li rich Mn, Ni, and Fe composite oxide materials, but pure rhombohedral phase cannot be obtained without excess Li in the stoichiometric LiMO2 form. The pure monoclinic phase Li2MnO3 is also synthesized to confirm its presence in the composite oxide cathodes. Particle size and surface morphology are studied with scanning electron microscopy. The composite cathodes are cycled to over 100 cycles at 0.3C, for C = 250 mAhg-1 rate. XAS before and after 100 electrochemical cycles of Li rich Mn-Ni-Fe based cathodes is reported for the first time. The determination of fractional contents of monoclinic and rhombohedral phases in the composite oxide cathodes is not possible by powder XRD analysis, however, Li2MnO3 content decreases on decreasing Mn content and on increasing Ni content. The composition with higher Ni content has a higher degree of cation mixing. The synergistic effect of rhombohedral and monoclinic phases in Li rich Mn, Ni, and Fe based cathode is critical for stable electrochemical performance. The Li1.2Mn0.50Ni0.20Fe0.10O2 cathode showed the most stable cyclability performance (194 mAhg-1 first discharge capacity with 94 % capacity retention after 100 cycles at 0.3C rate) however, Li1.2Mn0.40Ni0.30Fe0.10O2 (220 mAhg-1 first discharge capacity with 57 % capacity retention) and Li1.2Mn0.55Ni0.15Fe0.10O2 (241 mAhg-1 first discharge capacity with 68 % capacity retention) cathodes showed higher 1st discharge capacity but poor cyclability under the same charge/discharge cycling.The XAS at Mn K-edge is used to explain the mechanism of Li2MnO3 activation for the improved electrochemical performance of Li rich Mn, Ni, and Fe oxide composite cathode, however Li2MnO3 contributed differently in different compositions. Synchrotron XRD and XAS measurements probed the lattice size expansion, which decreases the chemical potential of Li ions in the cathode on cycling leading to lower discharge voltage after cycling.
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- Title
- IRREGULAR GROWTH AND INTERFACIAL EFFECT IN THIN FILM MULTILAYER STRUCTURES FOR USES IN PHOTOCATHODE APPLICATIONS
- Creator
- Lee, ZhengRong
- Date
- 2021
- Description
-
Improving photocathode performance by increasing the electron density while lowering the angular spread of emitted electrons can improve...
Show moreImproving photocathode performance by increasing the electron density while lowering the angular spread of emitted electrons can improve particle accelerator performance, expanding the reach of both fundamental and applied science. Materials science expertise is needed to design new photocathodes with these desired properties. Nemeth, et al, determined that a multilayered photocathode structure consisting of MgO/Ag/MgO could be engineered for higher brightness and lower dispersion [Nemeth, et al, Phys. Rev. Lett. 104, 046801 (2010)]. The dispersion of the surface bands impacts the angular spread of the emitted beam, and the model predicted that the bands could be tuned by precisely controlling the layer thicknesses of the multilayer structure. We synthesized and probed this MgO/Ag/MgO system experimentally. We measured the work function, emittance, and quantum efficiency of multilayer photocathodes with different MgO layer thicknesses to compare with theoretical predictions. We observed that although the general trend was as predicted, the measurements and the model were not in exact agreement [Velasquez, et al, Appl. Surf. Sci. 360, 762 (2016)]. In this work, we have undertaken a study of the electronic structure of the interfaces to explore how these observed deviations may have originated. It is possible that the fabrication process leads to non-ideal interfaces compared to those constructed in the simulations. To study how the fabrication affects the interfaces, hard X-ray photoemission spectroscopy(HAXPES) was used to probe the chemistry of the buried interfaces within the thin film multilayer structure of Ag and MgO. In these multilayer structures, we observed that the silver layers were predominantly metallic. A small high binding energy (ΔE = 0.69 eV) peak was also observed in the Ag 3d core level in the samples. This peak is shifted in the opposite direction of the binding energy shift in silver oxides, suggesting that this peak is not due to the formation of silver oxides at the interfaces with the MgO. Two possible explanations for the origin of this peak then are charge transfer at the interface from the Ag to the oxide monolayer or the formation of silver nanoparticles during the growth process. Based upon simple depth profiling analysis, we postulate the former is the more likely explanation. In addition, the O 1s and Mg 1s core level indicated the presence of Mg(OH)2. The MgO layers react with H2O in the vacuum chamber or ideal gas used as a buffer during sample transfer. Since the theory predicts a strong dependence upon the number of MgO layers surrounding the Ag, the formation of Mg(OH)2 likely contributes to the non- ideal behavior, even given the similarity in the electronic structure to MgO (large band gap insulator) and Mg(OH)2. The speed at which this reaction occurs would significantly limit the lifetime and the utility of the MgO/Ag multilayer photocathodes. In order to custom engineer multilayer photocathodes, complete control over the growth process will be needed to ensure that the ideal surfaces are formed. Using non-reactive materials would greatly increase the lifetime of the engineered photocathodes.
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- Title
- INVESTIGATION OF STRUCTURE AND PROCESSING EFFECTS ON THE ELECTROCHEMICAL PERFORMANCE OF COBALT-FREE, LITHIUM- AND MANGANESE-RICH LAYERED OXIDE CATHODE FOR LIBS
- Creator
- Kucuk, Kamil
- Date
- 2021
- Description
-
Rechargeable Li-ion batteries (LIBs) have been widely used in a diverse range of energy storage systems because of their high energy and power...
Show moreRechargeable Li-ion batteries (LIBs) have been widely used in a diverse range of energy storage systems because of their high energy and power density, low self-discharge, and tolerable memory effect, compared to the conventional alkaline, lead acid, and nickel-cadmium (Ni/Cd) batteries. [2] Since not only cathodes materials control the energy density of a cell, but also the capacity of cathode material characteristically restricts the cell capacity (as well as about 40% of the cell cost results from the cost of cathode raw materials), the majority of studies on LIBs have been carried out on developing alternative cathodes with higher energy, lower cost, and more environmentally friendliness. [2], [3] From this perspective, both Co-free and lithium- & manganese-rich (LMRO) layered oxide MNF cathodes, Li1.2(MnxNiyFez)O2, have recently attracted great attention in lithium-ion battery (LIB) research for electric vehicles and energy storage devices due to their high capacities of over 250 mAhg−1 and being eco-friendly and inexpensive compared to the cobalt-based Li-rich Li1.2(NixMnyCoz)O2 and Ni-rich Li(NixMnyCoz)O2 (NMC), and LiCoO2 commercial cathodes. Replacing toxic and expensive Co in the LMRO cathodes with environmentally friendly and much cheaper Fe element has been extensively studied over the last two decades. It was suggested by Aryal, S. et. al., in 2018. [4] that the Li1.2(Mn0.50Ni0.20Fe0.10)O2 (MNF502010) Co-free LMRO MNF cathodes seem better in terms of capacity-retention with higher discharge capacity and less voltage fade compared to other MNF compositions. However, the MNF502010 cathode still suffers from its lower experimental capacity, compared to its expected theoretical capacity (270-455 mAhg−1), as well as capacity decay, voltage fade, poor rate capability, and thermal instability. In this dissertation, it is reported that comparable specific discharge capacity with less amount of voltage fading and capacity decay can be achieved by fluorine doping, synthesizing materials in large amounts (0.1 mol synthesis at least) with two-step firing, and then washing the obtained nanocomposites with H3PO4 to create Li3PO4 layer on the surface of bulk MNF composites. The specific discharge capacity and cycling performance of the Co-free MNF502010 cathodes were studied and enhanced by using and optimizing these approaches in this work for the first time. However, voltage fading and capacity decay are still remaining challenges, even if they are remarkably mitigated by applying these approaches. Structural changes due to layered to spinel transformation, less amount of monoclinic phase activation leading to structural deformation occurring after 1st charge, dissolution of the transition metals (TM), and oxygen release (loss of lattice oxygen) from the MNF material upon following electrochemical cycling at higher voltage (≥ 4.5V ) seem the main reasons behind these challenges, specifically the voltage fading and capacity decay.A series of fluorine-doped/undoped, Co-free MNF502010 nanocomposite cathode materials (Li1.2(Mn0.50Ni0.20Fe0.10)O2(1−x)F2x, briefly F-doped MNF) were synthesized by using a sol-gel technique. Firstly (Chapter 4), the fluorine was substituted for oxygen in the parent MNF compound in different fractions (0.00, 0.025, 0.05,0.075, 0.10, which means 0%, 2.5%, 5.0%, 7.5%, and 10%), in order to optimize the amount of fluorine for better performance; secondly (Chapter 5), a large batch (0.1mol, 10 times more than the previous batch) of 5%F-doped material was prepared by a modified sol-gel synthesis which is modified by heating at 700 ◦C for different time-periods; 7.5 hours (7.5h), 15 hours (15h, two-step firing, 7.5h + rest for 12h + 7.5h), instead of heating directly 15 hours (d15h), as done in the first chapter; finally (Chapter 6), H3PO4 treatment resulting in a non-uniform Li3PO4 layer on the bulk surface. These approaches were respectively applied on doped/undoped MNF502010 nano-composites, in order to overcome the challenges already mentioned above. Finally, the effects of these approaches on the structural, morphological, and electrochemical properties of MNF cathode materials were investigated by means of powder X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM) with energy dispersive X-ray (EDS) analysis, X-ray photoelectron spectroscopy (XPS), cyclic voltammetry (CV), galvanostatic charge-discharge cycling, and X-ray absorption spectroscopy (XAS, an element specific probe technique). Specifically, ex-situ XAS was performed at the Mn, Ni, and Fe K-edge and used to detect the changes both in the oxidation state of the transition metal (TM) ions and their local environments in order to get a better understanding of the improved performance of the composite materials, as well as their failure mechanism. Moreover, the EXAFS data were modeled to gain insight into the influence of these approaches on the electrochemical performance of both pristine (uncycled) and cycled electrodes (after the 100th discharge). From correlating the electrochemical performance of the modified/unmodified MNF nano-composite cathodes to their XANES and EXAFS analysis, the ability to achieve higher specific capacity is strongly dependent on the formation of a well-ordered layered structure and the amount of monoclinic component (Li2MnO3) activation resulting in higher redox-activity of the Mn cations. The long-term cyclability or capacity retention can be enhanced by heating the resulting powders with a two-step firing (instead of directly 15 hours) and washing them with 1wt%H3PO4 solution to create a Li3PO4 conductive and protective layer.
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- Title
- Synthesis and Processing of NaSICON Membranes with High Ionic Conductivity and Good Mechanical Strength
- Creator
- Chiang, Shan-Ju
- Date
- 2019
- Description
-
Natrium super ion conductors (NaSICONs), Na1+xZr2SixP3-xO12 (0 ≤ x ≤ 3) are compounds that commonly used as solid electrolytes and membranes...
Show moreNatrium super ion conductors (NaSICONs), Na1+xZr2SixP3-xO12 (0 ≤ x ≤ 3) are compounds that commonly used as solid electrolytes and membranes of sodium based batteries, or in gas sensors and fuel cells due to their high sodium ion conductivity, low thermal expansion, and ability to accommodate ions in the lattice. However, NaSICON with high relative density (> 97%) and minimum impurity phases is found to be very difficult to obtain. Furthermore, the cost of the general synthesis methods is a serious drawback. Multi-high-temperature heating procedures is often employed to increase the density and to attain the single phase NaSICON because the particle size and free ZrO2 are better reduced. This research explores the possibility of densification and synthesis of NaSICON in one high-temperature reaction through a novel process termed Integrated Mechanical and Thermal Activation (IMTA) and the co-sintering behavior as well as the NaSICON composite membranes from tape casting. The sintering temperature of NaSICON was decreased by mechanical activation at room temperature using high-energy ball milling. Sintered NaSICON-based materials showed highest total ionic conductivity of 1.45 × 10-3 S cm-1 at room temperature and high density of 3.155 g cm-3 (96.5%). An alternative to obtaining full densification (99%) of NaSICON ceramics was developed utilizing traditional solid-state reaction. This sintered NaSICON without any sintering aid exhibited the total conductivity, 6.59 × 10-4 S cm-1 at 25 °C, and the highest density of 3.238 g cm-3, a better than 2.6% enhancement from the original samples.The second part of the work has comprised of successful fabrication of NaSICON/polymer composite membranes and bi-layered NaSICON/stainless steel membranes to enhance the mechanical flexibility of pure NaSICON films. The effect of different particle sizes of stainless steel on the sintering behavior and shrinkage rate were studied systematically. The effect of solid content in the slurry was also studied to control the density of both support layer and NaSICON body. The affect structural ratios have on co-sintered tapes along with ionic conductivity was investigated using Electrochemical Impedance Spectroscopy (EIS). The co-sintered membrane exhibited a total conductivity as high as 4.580 × 10-4 S/cm at room temperature. EIS results showed the high Na-ions conductivity strongly depends on the feature of grain boundary and the high densification of NaSICON layer.
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- Title
- DATA-DRIVEN FIRST-PRINCIPLES STUDY OF ORDERING PHENOMENA IN COMPLEX ALLOYS
- Creator
- Kim, George
- Date
- 2021
- Description
-
Determining the chemical (dis)ordering behavior in materials such as high entropy alloys (HEAs), and ternary Laves phases is fundamental to...
Show moreDetermining the chemical (dis)ordering behavior in materials such as high entropy alloys (HEAs), and ternary Laves phases is fundamental to developing structure-property relations that can be used as guiding principles for alloy design. A common obstacle in materials engineering is that an improvement of a material property comes at the expense of some other desirable properties. For example, trade-offs may be made between strength and ductility, or strength and density, etc. The large compositional and configuration space of possible HEAs, and Laves phases contain potential candidate materials with a balance of optimized properties and tunable structural and functional properties. However, fully exploring the large compositional and configurational space with experimental or even high-throughput Density Functional Theory (DFT) approaches is infeasible, and as of yet, predictive rules for phase stability and chemical (dis)order in HEAs, and Laves phases are still open questions.In this thesis, a HEA with chemical disorder, Al0.3CoCrFeNi, was studied using complementary experimental, DFT, and ML methods. The chemical disorder within the HEA resulted in a severely distorted lattice leading to a reduction in stiffness. Temperature dependence of chemical ordering behavior is studied in NbTaTiV and NbTaTiVZr HEAs using Monte Carlo (MC) simulations, which predicts short-range ordering (SRO) as well as short-range clustering (SRC) behavior in both HEAs. The compositional dependent behavior of substitutional ordering in two ternary Laves phases is evaluated and compared using cluster expansion (CE) models and Monte Carlo (MC) simulations.
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- Title
- NANOMATERIALS FOR ADVANCED BATTERY CATHODES
- Creator
- Moazzen, Elahe
- Date
- 2020
- Description
-
Cathode materials are key components that directly determine the power density of a battery. One of the most effective ways of developing high...
Show moreCathode materials are key components that directly determine the power density of a battery. One of the most effective ways of developing high power density cathodes is bringing them into the nano-scale world, which results in many expected and unexpected properties. Some of the desired characteristics include faster charge/discharge kinetics, improved capacity retention and structural stability due to the higher surface to volume ratio and shorter ion diffusion paths. In this dissertation a number of uniquely designed nano-sized cathode materials and nanocomposites are developed and investigated for alkaline aqueous and lithium ion battery applications. Nickel hydroxide (Ni(OH)2), which is one of the most important cathode materials in alkaline batteries, suffers from low conductivity, which usually leads to inefficient discharge and incomplete utilization of the material. A series of Ni(OH)2/Co(OH)2 core/shell nanoplatelets were synthesized and systematically investigated as cathode materials. Structure-property correlations revealed that electrochemical behavior and reversibility of Co(OH)2 redox conversion depended non-linearly on the average shell thickness, with the best performance (99.6% of theoretical capacity of the composite material) achieved at shell thickness of 1.9 ± 0.3 nm. Two fundamental phenomena were suggested to be responsible for the superior performance: templated shell deposition and galvanic coupling of core and shell materials.Manganese (IV) oxide (MnO2), which is another practical cathode that has a great potential to be utilized for a variety of energy storage systems, still has some major challenges including reversible cycling in rechargeable batteries. One of the most crucial challenges is the fact that polymorphs of MnO2 have different electrochemical activities as aqueous and Li-ion battery cathodes. However, most synthetic samples contain a mixture of polymorphs, which makes the structure-property correlations more complicated. This dissertation reports on systematic studies correlating synthesis, thermal and mechanical processing, and composite formation with polymorph composition, electrochemical performance and ion intercalation mechanisms. Among all the results, several main conclusions were reached: 1) Through control of the synthesis parameters and post-processing, desired phase compositions and nanoparticle morphologies, which optimize MnO2 performance in aqueous alkaline electrolyte, can be achieved. Nanoparticles with higher fraction of the akhtenskite polymorph showed higher reversible capacities in LiOH electrolyte (~210 mAh g-1), with stable performance for over 50 cycles. The effects of sub-nanoparticle organization of MnO2 polymorphs by thermal treatment without any morphology change on cycling performance, phase activation, and charge/discharge mechanisms in LiOH electrolyte as well as the detailed mechanism of the polymorph conversion during annealing were studied and for the first time, demonstrating that the electrochemical activity of MnO2 material strongly depends not only on the lattice structure of individual polymorphs but also on the sub-nanoparticle polymorph architecture and interphases.2) Several processing strategies, including thermal and mechanical processing, and composite fabrication were utilized to develop functional MnO2 cathodes for Li-ion batteries. Improvements in capacity and cycling performance were correlated to the presence of the pyrolusite phase of MnO2 and the crystallite size. Composite fabrication by graphene oxide wrapping also provided significant performance improvements through polymorph composition control and improved conductivity.
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- Title
- FUNCTIONALIZED NANOSCALE MATERIALS FOR PROTEIN BIOMARKER DETECTION
- Creator
- Zhang, Youwen
- Date
- 2020
- Description
-
Proteins are vital biomolecules in living organisms which function as the working element for many aspects of life. An abnormal expression of...
Show moreProteins are vital biomolecules in living organisms which function as the working element for many aspects of life. An abnormal expression of proteins or expression of unique proteins is often associated with certain disease. Accordingly, proteins have become valuable biomarkers for disease diagnosis and prognosis. So far, numerous methods have been developed for detections of protein biomarkers. However, most of them suffer from the lack of accuracy, sensitivity, and specificity for clinical diagnostic applications. With the rapid advancement in nanotechnology, functional nanoscale materials, which could overcome the biocompatibility and biological recognition ability, have been widely used to develop sensitive and selective biosensors.In this dissertation, two kinds of functionalized nanoscale materials-based sensing strategies are investigated for protein biomarker detection. One strategy takes advantages of graphene oxide (GO) and utilizes fluorescence resonance energy transfer (FRET) for fast and sensitive protease detection by covalent attaching fluorescently labeled protease substrate peptide to the GO surface. This type of GO-based fluorescence sensor is highly sensitive (with a detection limit of picomolar concentration) and selective (other structure similar proteases does not interfere with the target analyte detection). In addition, it could accurately analyze serum samples. With this strategy, we have successfully achieved the detection of the HIV-1 PR (HIV-1 protease, a significant biomarker for AIDS) and ADAMs (a disintegrin and metalloproteinases, a biomarker for human cancers). It could be visualized that this GO platform could be utilized to detect various proteases by only changing the peptide substrate and solution pH. In addition, by coupling multiple substrate peptides on the GO surface, we developed a multiplex GO sensing system for simultaneously profiling of the activities of a panel of MMPs/ADAMs. Under the assistance of joint entropy and programming, our sensor could identify up to 5 types of human cancers, and offers the potential to detect other cancer types by changing biomarkers.The other strategy is to utilize nanopore stochastic sensing to detect proteins, which involves measuring the ionic current modulation generated by analytes’ electro-osmotic flow through a chemical functionalized nanoscale sized pore. As a sensitive and label-free technique, nanopores have been highly recognized as one of the emerging techniques to detect analytes at the single-molecule level. Unlike DNA molecules which are uniformly charged, proteins are an isotropically charged molecules, which have low translocation probability through a nanopore. Since the protein pore-based sensing system is not suitable as deployable tools for detection of proteins due to the size limitation and fragile nature of the biological membranes. In this project, we fabricated solid-state nanopores using PET membranes followed by chemical functionalization of their inner surfaces. The modified- PET nanopore was sensitive and could detect HIV-1 protease at picomolar concentration. More importantly, the modified-nanopore sensor was selective, and could differentiate the target protein from others such as Trypsin, BSA and HSA. Furthermore, the modified PET nanopore strategy developed in this work provide a general platform for exploring fundamental protein dynamics and rapid detection of proteins at the single-molecule level
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- Title
- SI NANOSTRUCTURED COMPOSITE AS HIGH PERFORMANCE ANODE MATERIAL FOR NEXT GENERATION LITHIUM-ION BATTERIES
- Creator
- He, Qianran
- Date
- 2019
- Description
-
Silicon has attracted huge attention in the last decade as the anode material for Li-ion batteries because it has a theoretical capacity ∼10...
Show moreSilicon has attracted huge attention in the last decade as the anode material for Li-ion batteries because it has a theoretical capacity ∼10 times that of graphite. However, the practical application of Si is hindered by three major challenges: large volume expansion during cycling (∼300%), low electrical conductivity, and instability of the SEI layer caused by repeated volume changes of the Si material. Our study focused on novel design and synthesis of Si anodes that can solve all the key problems of Si anodes simultaneously. The Si micro-reactors we designed and synthesized contain well-designed internal structures, including (i) nanoscale Si building blocks, (ii) the engineered void space, and (iii) a conductive carbon shell. Because of these internal structures and nitrogen doped carbon shell, these sub micrometer-sized Si particles are termed as Si micro-reactors and denoted as Si@void@C(N). According to our electrochemical results, the as-synthesized Si micro-reactors could live up to 1000 charge/discharge cycles at high current densities (up to 8 A/g) while still providing a higher specific capacity than the state-of-the-art carbonaceous anodes. Our investigation shows that the unique design of Si@void@C(N) has a relatively low specific surface area (SSA) which significantly reduces the undesired surface side reactions and increases ICE to 91%, while the engineered voids with nano-channel shape inside the structure can accommodate Si volume expansion and keep the structure and SEI layer stable. Furthermore, the porous N-doped carbon shell along with nano-channeled voids allows rapid lithiation of the Si micro-reactor without Li plating during ultrafast charging. As a result, Si@void@C(N) exhibits ultrafast charging capability with high ICE, superior specific capacity and long cycle life.
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- Title
- IN SITU X-RAY ABSORPTION SPECTROSCOPY STUDY OF TIN-BASED GRAPHITE COMPOSITE ANODES FOR LITHIUM-ION BATTERIES
- Creator
- Ding, Yujia
- Date
- 2019
- Description
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Sn-based anode materials such as Sn, SnO2, Sn4P3, and SnS2 that exhibit large theoretical capacities are promising alternatives to traditional...
Show moreSn-based anode materials such as Sn, SnO2, Sn4P3, and SnS2 that exhibit large theoretical capacities are promising alternatives to traditional graphite anodes for Li-ion batteries. However, their capacities fade drastically in a few cycles due to substantial volume changes during the lithiation/delithiation process resulting in cracking and pulverization of the electrode. A graphite matrix is introduced by high-energy ball milling to obtain a graphite composite and enhance the electrochemical performance. Indeed, Sn4P3/graphite composite exhibits a reversible capacity of 651 mA h g-1 in the 100th cycle, and SnS2/graphite composite shows 591 mA h g-1 in the 50th cycle.To obtain a better understanding of the improved performance of the composite materials and the reason for the more gradual capacity fading, in situ EXAFS is used to investigate these mechanisms using in situ coin cells and in situ vacuum-sealed pouch cells. The collected EXAFS data were analyzed by modeling to extract detailed local environment changes during the lithiation/delithiation process.In the crystalline phases of Sn-based materials, the conversion reaction forming metallic Sn is partially reversible and partially irreversible, and the subsequent alloying/dealloying reaction forming LiSn alloys is reversible. Introducing the graphite matrix increases electrical conductivity and prevents aggregation of intermediate Sn clusters. The graphite matrix also plays a significant role in transforming composites into highly dispersed amorphous phases. These amorphous phases, formed in the first few cycles of Sn4P3/graphite and SnS2/graphite composites, exhibit excellent reversibility in both conversion and alloying/dealloying reactions, which is the main reason for the significant improvements in electrochemical performance. The slow growth of metallic Sn clusters and the slight reduction in amorphous phases result in gradual capacity loss over long-term cycling. Introducing the graphite matrix and creating highly dispersed composite samples are the successful strategies that can be scaled up to develop new battery materials in the future.
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- Title
- Effects of Microstructure Engineering on Laser Powder Bed Fusion Processed Superalloy IN718 through Inoculant Addition
- Creator
- Ho, I-Ting
- Date
- 2023
- Description
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Additive manufacturing (AM) techniques can now be utilized as innovative tools that provide unlimited design flexibility for the fabrication...
Show moreAdditive manufacturing (AM) techniques can now be utilized as innovative tools that provide unlimited design flexibility for the fabrication of geometrically complex metallic structures. For production of Ni-base superalloy components used in advanced gas turbine engines, laser powder bed fusion (L-PBF), which is one of the AM techniques, is frequently used as it allows good metallurgical bonding of powder feedstock and simultaneously enables development of ultra-efficient power systems for aerospace propulsion, space exploration and power generation. One of the major challenges associated with additively manufactured Ni-base superalloy components is that the extreme temperature gradients encountered during processing negatively impact the underlying microstructure and mechanical properties of the material. Although the macroscopic shape and chemistry of the additively fabricated part may be identical to the conventionally manufactured part, the resulting properties are usually compromised. In an effort to make Ni-base superalloys more amenable for processing via additive manufacturing, varying levels of benign inoculants that promote may heterogeneously grain nucleation were blended into Inconel 718 (IN718) powder feedstock and used for processing via L-PBF to characterize the microstructural evolution. In the first study, 0.2 wt. % of micron-sized CoAl2O4 flakes was found to effectively change the grain morphology during the L-PBF process leading to significant reduction in crystallographic texture and thus resulting elastic anisotropy. Dispersion of nano-oxides resulting from the reduction of CoAl2O4 particles also contributed to improved tensile strength and steady creep strain rate. It should be noted, however, that, the multiple iterations of remelting as the result of deposition of new layers dissolved the Co-rich particles reduced from CoAl2O4 inoculants. Instead of having nucleation events contributed by elemental Co, the oxide agglomerates as a result of Marangoni convection seemed to be the major contribution to facilitating grain refinement by inhibiting the heat transfer in the surroundings. On the other hand, addition CoAl2O4 particles appeared to generally reduce the melt pool width while increase the melt pool depth by inhibiting the degree of heat transfer and Marangoni flow. The changes in melt pool dimension aided in improving the relative density and surface roughness of the bulk samples by generating better metallurgical bonding to the subsequent layers. As the trade-off, however, the changes in melt pool physics also enhanced the tendency for epitaxial growth and hence retarded the columnar-to-equiaxed transition unless oxide agglomerates are present. In addition to CoAl2O4, candidates including Co, TaCr2, TiB2, and CeO2 particles were also considered to be blended with the powder feedstock of IN718. After the L-PBF process, different degree of microstructural evolution was characterized with the addition of Co, TaCr2, TiB2, or CeO2 particles. It was found that the physical presence of inoculants may change the melt pool geometries that accounted for a comparatively more columnar-grained structure with <101> texture in samples containing Co and TaCr2 particles while a relatively equiaxed-grained structure with <001> texture in samples containing TiB2. The comparison between samples containing TiB2 and CeO2 further indicates that the phase transformation induced agglomeration will also reduce the effectiveness of inoculants due to decreasing nuclei density. Findings from this investigation demonstrate the resulting grain structure upon L-PBF can be profoundly impacted by both chemistry and physical properties of the inoculants. These effects may potentially be harnessed to effectively engineer the microstructure and optimize the properties of L-PBF processed Ni-base superalloys.
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- Title
- Melt Growth of Indium-Iodide on Earth and in Microgravity
- Creator
- Riabov, Vladimir
- Date
- 2023
- Description
-
Indium Iodide is a heavy metal halide and a wide band-gap semiconductor which has a potential for application in room temperature γ- and X-ray...
Show moreIndium Iodide is a heavy metal halide and a wide band-gap semiconductor which has a potential for application in room temperature γ- and X-ray detectors. Its physical properties are similar to those of other materials used as room temperature radiation detectors. Over the years the technology of purification and crystal growth of InI was developed. Significant advances were made to improve purity, crystal structure and resulting electronic properties of the material. Nevertheless, the desired detector performance has not been achieved yet. Stress-induced crystal lattice defects resulting from solidification in contact with crucible are suspected to be responsible for the limited performance. Microgravity environment was previously used to study its effects on the process of crystal growth from the melt applied to semiconductors. It was observed that unlike on Earth materials can solidify without contact with the wall, when the sample is confined by the crucible. It was also shown that such detached solidification can drastically reduce stress-induced defects of the crystal lattice and improve electronic properties of the material. In this study crystal growth of InI was studied in microgravity, attempting to achieve detached solidification, and observe it in a transparent zone of a furnace. Partially detached solidification (a large free surface) has occurred in one of the samples. The resulting crystals were characterized by measuring their electronic properties and estimating the radiation detector performance of the devices manufactured using the crystals.
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- Title
- New Insights to Thermoelectrics from Fundamental Transport Properties to Potential Materials and Device Design
- Creator
- Pan, Zhenyu
- Date
- 2022
- Description
-
Thermoelectric (TE) materials have been widely studied as their ability to make direct energy conversion between heat and electricity. However...
Show moreThermoelectric (TE) materials have been widely studied as their ability to make direct energy conversion between heat and electricity. However, the conversion efficiency is still low compared with conventional devices no matter in power generation or electrical cooling. Therefore, most efforts have been made to improve the zT of TE materials, which is the commonly accepted metric for determining the performance of TE materials. But the progress is slow as the key parameters governing the zT is interrelated to each other which makes improving one often at the cost of the others leading to a narrow use of TE applications. Thus this thesis does not confine itself only in searching for high zT TE materials but also exploring useful things which are buried or ignored in previous thermoelectric researches from fundamental transport properties to TE device design. Firstly, we reevaluated the photo-Seebeck effect, which has been known for decades, and demonstrated that it is a powerful tool for semiconductor study as it allows the determination of mobilities, photo-carrier densities, even weighed mobilities (hence effective masses) of both electrons and holes and impact of defects all from a single sample. We then investigated a newly discovered low dimensional material, 2D tellurene, which has the potential to decouple the interrelated parameters to achieve a high zT. Lastly, we reconsidered the question that whether zT is the only merit index determining TE device performance. We hope this thesis can shed some light on thermoelectrics both from fundamental transport properties to device design.
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- Title
- MICROSTRUCTURE AND MECHANICAL PROPERTIES OF DISCONTINUOUSLY PRECIPITATED NI-CO-AL ALLOYS
- Creator
- Ho, Kathy
- Date
- 2022
- Description
-
The study of high temperature structural materials has been one of great interest and immense focus in recent years of research and...
Show moreThe study of high temperature structural materials has been one of great interest and immense focus in recent years of research and development. With the capability of catering to specific needs and applications while being commercially cost-effective, these materials can be synthesized using various types of methods and materials for a large range of applications. In order to implement the advantageous properties of these materials for practical use in service, empirical data relating to the material and mechanical properties of these high temperature structural alloys must first be obtained. This can be achieved through numerous processing methods. One particular method involves precipitation strengthening. Two types of transformation modes include discontinuous and continuous precipitation. Discontinuous precipitation (DP) nucleates at high angle, incoherent grain boundary, grows through grain boundary diffusion, and produces a lamellar structure consisting of alternating layers of γ and γˡ (Ephler, 2004). Continuous precipitation (CP) nucleates within the grain, is controlled through volume diffusion producing, and results in a homogeneous distribution of equilibrium composition precipitates with a spherical/cuboidal morphology. Since both modes of transformation possess a chemical driving force, resulting from the supersaturation of solute, the coexistence of both DP and CP transformation in a material is possible. However, as demonstrated from past studies, the presence of a partial DP transformation in structural alloys is undesirable as detrimental effects on mechanical properties are observed. As a result, numerous studies have focused on suppressing DP all together. In 1972 Erhard Hornbogen hypothesized that a fully DP transformed material would yield superior mechanical properties, similar to pearlite formation in steel, since the lamellar structure would increase barriers to dislocation movement (Hornbogen, 1972). As a result, recent studies have redirected their focus in an effort to encourage DP transformation to completion for improved mechanical properties. Therefore, the purpose of this work was to 1) determine the aging conditions under which a complete, 100% DP transformation would be achieved in select alloys, 2) determine the conditions where optimal precipitate size via CP transformation is obtained to effectively use precipitation strengthening without the concern of over-aging, 3) experimentally compare the material and mechanical properties between 100% DP aged samples and CP aged samples consisting of the optimal precipitate size, 4) compare the mechanical properties between alloys that have undergone a complete DP transformation to commercial alloys currently used in service, and 5) provide empirical data to verify Hornbogen’s claim. The results from this work indicated that 1) a lower aging temperature promote DP transformation while a higher temperature promotes CP transformation, 2) a smaller grain size prior to aging was more favorable for DP transformation while larger grains were favorable for CP transformation, 3) a complete DP transformation was observed for Alloy 9 and Alloy 10 after aging at 500°C for 4 hours and 550°C for 4 hours, 4) Alloy 1, Alloy 3, and Alloy 5 were potentially undergoing a different type of transformation at lower DP aging temperatures, where β phase was present, 5) optimal precipitate size for effective use of precipitation strengthening (CP transformation) was achieved under CP aging conditions 700°C-1HR for Alloy 10 and 750°C-1HR for Alloy 9 and the forged stock bar, 6) a small fraction of DP consistently formed at the grain boundaries of the CP aged samples for all alloy samples, indicating that the nucleation of DP was quick, but growth was limited, 7) mechanical properties of the DP aged samples for Alloy 9, Alloy 10 and the forged bar were superior to their corresponding CP aged samples in terms of the hardness, UTS, and yield stress, but were less ductile than the CP aged samples, and 8) the mechanical properties of DP aged samples for Alloy 9, Alloy 10, and the forged bar were comparable, and at times superior, to the commercially available alloys. Due to limited prior research conducted on the mechanical properties of DP alloys, this investigation serves as a pioneering effort experimentally determine if the mechanical properties of completely DP transformed material are superior to that of CP transformed material, aged to optimal precipitate size, while collecting empirical data to verify Hornbogen’s claim.
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- Title
- EXAMINING PERFORMANCE DEGRADATION OF LI-ION BATTERIES WITH SILICON-BASED ANODE AND POSSIBLE SOLUTIONS TO IMPROVE THE SILICON ANODE BEHAVIOR
- Creator
- Luo, Mei
- Date
- 2022
- Description
-
Si has been investigated as a promising alternative to conventional graphite because of its high specific capacity and wide operating voltage;...
Show moreSi has been investigated as a promising alternative to conventional graphite because of its high specific capacity and wide operating voltage; however, technical challenges related to volume change in the silicon anode have hampered their practical application. In this work, the effects of silicon volume change on electrochemical performance has been studied in NMC532/Si full cells. First, different area specific capacity ratios of the negative to positive electrode (N:P ratio) were investigated using three-electrode cells. With individual electrode potentials monitored by a reference electrode, different depths of lithiation/delithiation at the anode and cathode were found to play an important role on cell performance; the cell with higher N:P ratio displays superior electrochemical performance due to its smaller silicon volume change. Further, calendar-life aging and cycle-life aging of NMC532/Si cells were compared with their electrode potentials monitored using a reference electrode. The observation of larger capacity decay and impedance growth of cycle-life aging cells illustrates the important effect of silicon volume change; significant capacity decay of calendar-life aged cell was observed as well, revealing an essential role of chemical effect of ongoing side reactions at Si anode. Specially-designed silicon with different protocols and electrolyte additives were investigated to address the intrinsic challenges of Si anodes for lithium-ion batteries.
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- Title
- Stimulation-Responsive Materials for the Treatment of Disordered Tissues
- Creator
- Clutter II, Elwin Dean
- Date
- 2022
- Description
-
Microenvironments offer physical and chemical cues to cells that affect their behavior. These cues can be bioactive chemicals such as drugs...
Show moreMicroenvironments offer physical and chemical cues to cells that affect their behavior. These cues can be bioactive chemicals such as drugs and cytokines, matrix cues like stiffness and composition, and electrical signals as seen in membrane potentials and epithelial wound healing. Controlling these cues can drive cell behavior toward apoptosis, proliferation, or changes in protein expression. In this thesis research, three components were used to model changes in cell behavior: the near infrared dye indocyanine green (ICG), silk fibroin (SF) from Bombyx mori silkworm cocoons, and carbon nanotubes (CNT). The mechanism of ICG photobleaching was studied for the efficacy to kill neuroblastoma cancer cells. ICG was twice as effective at killing neuroblastoma than fibroblast cells. Albumin stabilized monomeric ICG to enhance photobleaching by improving light interaction, and photodegradation of ICG into α,β-unsaturated aldehydes led to significant reduction of proliferation in neuroblastoma cells by targeting cell signaling components such as protein transcription factors. SF-ICG composite materials were developed into films and electrospun fibers. These composite materials were examined as light-activated wound coverings to control bleeding in hemorrhage, using ICG’s photothermal effect. ICG added an absorbance peak to SF at 805 nm. Irradiation decreased this peak, produced a new absorbance peak at 352 nm, and an increased fluorescence peak around 490 nm, showing photochemical changes that may be useful in sensor design. Increased heat production from irradiation of SF-ICG occurred in the films with 0.2% w/w ICG in SF during 1 min irradiation, whereas SF-ICG fibers required improvement of processing by ethanol vapor treatment (EVT) to reduce loss of ICG during preparation. EVT improved ICG retention in SF fibers during sterilization with 70% ethanol solution thus improving heat generation in the SF-ICG fibers. Heat evolved from SF-ICG 0.2% film solidified bovine blood within 42 s, with visible changes after the first 6 s. SF electrospun fibers were investigated to optimize silk preparation to reduce diameters and increase alignment to mimic local native cell environments with and without CNT to add conductivity for enhancement of electrical stimulation. CNT reduced SF fiber diameters below 1% and effected alignment differently as the concentration increased. Longer degumming times decreased SF fiber diameters and alignment of the same concentration. The optimized conditions were 1 h degumming time with 1.5 ml/h flow rate at a concentration of 100 mg/ml spinning solution with 0.25% CNT to form fibers with 1.36 (± 0.09) µm diameter and 0.31 (± 0.01) a.u. alignment. Additionally, SF fibers were used as a long-term cell growth scaffold to compare with decellularized native tissue. Decellularized tissue decreased fibroblast mRNA expression of collagen type 1, lysyl oxidase-like 1 and matrix metalloproteinase 9, while all other genes expression was the same as cells on plastic. The SF fiber scaffold reduced fibroblast expression of collagen type 3 compared to growth on plastic, and both collagen types 1 and 3 increased over growth time on SF. Immunofluorescence staining showed both collagens newly deposited on the SF scaffold and improved over time. In conclusion, proteins stabilized ICG monomers to improve light interaction, efficacy of photobleaching, and heat evolution to induce apoptosis in neuroblastoma and agglutination of blood in SF composites. Irradiation of ICG enhanced changes in optical properties and may have sensor applications. The decrease of genes may be due to each scaffold having lower stiffness compared to plastic. ICG and SF are both materials with applications as biological scaffolds in pelvic organ prolapse and treatment of neuroblastoma and hemorrhage.
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- Title
- Towards Understanding the Microstructure and Mechanical Properties of Additively Manufactured Ni-base Superalloys
- Creator
- Tiparti, Dhruv Reddy
- Date
- 2022
- Description
-
Nickel-base superalloy components such as turbine discs typically undergo numerous manufacturing steps that contribute to increasing the cost...
Show moreNickel-base superalloy components such as turbine discs typically undergo numerous manufacturing steps that contribute to increasing the cost and the waste of excess materials. With advent of fusion based additive of manufacturing (AM) techniques, such components with complex geometry can be fabricated with great efficiency. However due to characteristically high energy densities, fast cooling rate, and layer-by-layer building process associated with AM; Ni-base superalloys with higher temperature performance are difficult to be fabricated by AM due to susceptibility to composition related defect formation, which is further exacerbated by anisotropic grain structures induced by the large thermal gradients present. Crack-free material can be fabricated but, in most cases, issues such as an anisotropic microstructure will prevail, and the balance of mechanical properties achieved may not be suitable for the desired applications. Several strategies exist to mitigate the challenges posed by additive manufacturing via post-processing such as hot-isostatic processing, annealing heat treatments, application of grain refining inoculants, etc. All these strategies utilized to mitigate issues with AM of Ni-base superalloys still require further study to understand their effects on the microstructure and mechanical properties. This work aims to evaluate the use of inoculant particles, and novel heat treatments on the microstructure and mechanical properties of different superalloys. First, the effect of varying amounts of CoAl2O4 inoculant ranging from 0 to 2 wt.% on the microstructure evolution of Inconel 718(IN718) fabricated by selective laser melting (SLM) was evaluated. The findings from this study indicated that additions of CoAl2O4 only resulted in a minor degree of grain refinement with slight increase in anisotropy; in addition, a CoAl2O4 ¬content above 0.2 wt.% resulted in the formation of agglomerate inclusions; and that to effectively utilize CoAl2O4 as a grain refining inoculant, process parameters must be further optimized while considering the formation of agglomerates, and other defects. Second, the application of CoAl2¬O4 was extended towards the Direct Energy Deposition (DED) of IN718. Here findings indicated that due to the modification of the thermophysical properties of the melt pool by oxide addition, an earlier onset of large columnar extending across multiple layers occurred while counteracting conditions required for equiaxed grain formation; and these CoAl2O4 were also found to exhibit a potent Zenner pinning effect that maintained the as-built grain structure despite application of extreme high treatment condition of 1200oC for 4 hrs. Third, the tensile and fatigue properties of the DED IN718 with CoAl2O4 were evaluated. Here, it was found that the addition of CoAl2O4 leads to a minor increase in tensile strength in the as-built condition attributed primarily to the fine oxide dispersion; a more modest increase in tensile strength in the heat-treated condition due to grain refinement induced by retaining the as-built grain structure; and that despite the increase in tensile strength with CoAl2O4 a corresponding increase in fatigue life did not occur. Lastly, the processing of René 65 conducted by laser-powder bed fusion(L-PBF) was done and compared to the conventionally cast and wrought material. Here, the effect of the difference in processing route in conjunction with heat treatments was evaluated to understand the creep and stress relaxation behavior. It was found that L-PBF of René 65 led to an overall improved resistance to deformation by creep and relaxation mechanism.
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- Title
- Using Niobium surface encapsulation and Rhenium to enhance the coherence of superconducting devices
- Creator
- Crisa, Francesco
- Date
- 2024
- Description
-
In recent decades, the scientific community has grappled with escalating complexity, necessitating a more advanced tool capable of tackling...
Show moreIn recent decades, the scientific community has grappled with escalating complexity, necessitating a more advanced tool capable of tackling increasingly intricate simulations beyond the capabilities of classical computers. This tool, known as a quantum computer, features processors composed of individual units termed qubits. While various methods exist for constructing qubits, superconducting circuits have emerged as a leading approach, owing to their parallels with semiconductor technology.In recent years, significant strides have been made in optimizing the geometry and design of qubits. However, the current bottleneck in the performance of superconducting qubits lies in the presence of defects and impurities within the materials used. Niobium, owing to its desirable properties, such as high critical temperature and low kinetic inductance, stands out as the most prevalent superconducting material. Nonetheless, it is encumbered by a relatively thick oxide layer (approximately 5 nm) exhibiting three distinct oxidation states: NbO, NbO$_2$, and Nb$_2$O$_5$. The primary challenge with niobium lies in the multitude of defects localized within the highly disordered Nb$_2$O$_5$ layer and at the interfaces between the different oxides. In this study, I present an encapsulation strategy aimed at restraining surface oxide growth by depositing a thin layer (5 to 10 nm) of another material in vacuum atop the Nb thin film. This approach exploits the superconducting proximity effect, and it was successfully employed in the development of Josephson junction devices on Nb during the 1980s.In the past two years, tantalum and titanium nitride have emerged as promising alternative materials, with breakthrough qubit publications showcasing coherence times five to ten times superior to those achieved in Nb. The focus will be on the fabrication and RF testing of Nb-based qubits with Ta and Au capping layers. With Ta capping, we have achieved the best T1 (not average) decay time of nearly 600 us, which is more than a factor of 10 improvements over the bare Nb. This establishes the unique capping layer approach as a significant new direction for the development of superconducting qubits.Concurrently with the exploration of materials for encapsulation strategies, identifying materials conducive to enhancing the performance of superconducting qubits is imperative. Ideal candidates should exhibit a thin, low-loss surface oxide and establish a clean interface with the substrate, thereby minimizing defects and potential sources of losses. Rhenium, characterized by an extremely thin surface oxide (less than 1 nm) and nearly perfect crystal structure alignment with commonly used substrates such as sapphire, emerges as a promising material platform poised to elevate the performance of superconducting qubits.
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