Heusler alloys are compounds based on the original Heusler phase Cu2MnAl which are ternary intermetallics with a particular chemical... Show moreHeusler alloys are compounds based on the original Heusler phase Cu2MnAl which are ternary intermetallics with a particular chemical stoichiometric formula X2YZ and face-centered cubic structure. Heusler alloys are of interest because of a range of physical phenomena which may occur in them that can be applied in mechanical or electronic devices, including shape memory property and disorder/order phenomenon. In this work, a high temperature drop calorimeters and Setaram calorimeters were used to obtain the enthalpy of formation and heat capacity of compounds in the Mn-based Heusler compounds (X2MnZ). Lattice parameters of these compounds were determined with XRD, and phase equilibria in these alloy system were studied in this work. Phase transformations were studied with DSC and dilatometry. The work is aimed at populating databases for computational thermodynamics, developing an understanding of alloying and clarifying phase equilibria. M.S. in Material Science and Engineering, July 2012 Show less
