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FABRICATION, CHARACTERIZATION AND RELEASE STUDIES OF LOW DENSITY POLYETHYLENE/CLAY NANOCOMPOSITES
Title
FABRICATION, CHARACTERIZATION AND RELEASE STUDIES OF LOW DENSITY POLYETHYLENE/CLAY NANOCOMPOSITES
Creator
Zhao, Ziqian
Date
2015, 2015-07
Description
Nanocomposites exhibit enhanced physical properties including mechanical strength, thermal stability, and gas barrier properties. The...
Show moreNanocomposites exhibit enhanced physical properties including mechanical strength, thermal stability, and gas barrier properties. The development of nanocomposites has led to applications in food industry, mostly in food packaging. The application of nanocomposites in food packaging may extend the shelf life of a food, thus increasing the market value for manufactures. However, there is limited data and research to assess the risk of exposure of nanomaterials to consumers. This project aims at evaluating the factors that can influence the release of nanomateirals in low density polyethylene/clay nanocomposites films. Nanocomposites based on low density polyethylene (LDPE), containing 1, 3, 5 and 7 wt.% of Cloisite 20A and maleic anhydride-grafted polyethylene (MAPE) as a compatibilizer were prepared by melt compounding and characterized in this thesis project. Cloisite 20A is mostly composed of montmorillonite (MMT), which is commonly used as a nanoscale size filler. LDPE/Clay nanocomposite films containing MMT and three mass equivalents of MAPE were successfully extruded into thin films with good optical clarity. The materials were characterized by using transmission electron microscope (TEM), thermogravimetric analysis (TGA), oxygen permeation analysis and a material testing machine. Important properties such as tensile modulus, oxygen transmission rate, thermal resistance and glass transition temperature were measured. Nanocomposite films were immersed in three kinds of food simulants (absolute ethanol, 3% acetic acid and deionized water). Storage time, storage temperature and percent fill of clay were evaluated as the factors that can influence the release of nanomaterials. The content of released of Al, Mg, and Si was quantified using inductively coupled plasma mass spectrometry (ICP-MS). Mg, Al and Si were continuously released from nanocomposite films in duration of 30 days. Fastest releasing speed was found in 3% aqueous acid at 75 °C, and lower temperature can largely decrease the release of nanoparticles. This project is an initial attempt to assess the risks from the use of nanocomposites as food packaging.
M.S. in Food Safety and Technology, July 2015
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Migration of Silver from Silver Zeolite/Low-Density Polyethylene Films into Food Stimulants
Title
Migration of Silver from Silver Zeolite/Low-Density Polyethylene Films into Food Stimulants
Creator
Sayeed, Maryam
Date
2023
Description
Zeolites are naturally occurring or synthetic crystalline microporous aluminosilicate structures with remarkable catalytic, adsorption, and...
Show moreZeolites are naturally occurring or synthetic crystalline microporous aluminosilicate structures with remarkable catalytic, adsorption, and ion-exchange properties. Their unique framework of pores, channels, and cages with precise dimensions makes them an excellent fit for ion exchange and storage. Silver-exchanged zeolite (Ag/Y) composites may be incorporated into polymer matrices to create antimicrobial packaging materials. The slow release of Ag from nanosilver-enabled polymer nanocomposites (PNCs) may inhibit the growth of bacteria and other pathogens on the film’s surface, improving food quality and reducing food waste. However, the migration of Ag ions from the film into food matrices is of great concern as it could expose humans to high concentrations of a heavy metal from dietary sources. The amount of migration depends on various factors, including the potential form of Ag and its concentration in the film, the film thickness, and the storage conditions.The primary objective of this study is to investigate the effect of the form of Ag bound to the zeolite on the migration behavior of Ag from Ag/Y incorporated low-density polyethylene (LDPE) films. For Ag/Y-incorporated LDPE PNCs with distinct Ag species, the Ag migration into the water and Squirt (a commercial soft drink) was at least four times higher from films containing zeolites exchanged with ionic Ag versus zeolites exchanged with nanoparticulate Ag. Similarly, migration into 9 wt % aqueous Domino sugar (granulated sucrose) solution was seven times higher in the ionic silver-incorporated film than in the nanoparticulate Ag film. This study suggests that it is important to consider the form of Ag in silver-exchanged zeolite while producing packaging materials since the potential form of Ag in the PNCs might significantly affect Ag migration behavior.
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