Search results

(1 - 2 of 2)
SYNTHESIS OF HIGH PERFORMANCE SILICON ANODES AND SURFACE-MODIFIED NMC CATHODES FOR LI-ION BATTERIES
Title
SYNTHESIS OF HIGH PERFORMANCE SILICON ANODES AND SURFACE-MODIFIED NMC CATHODES FOR LI-ION BATTERIES
Creator
Ashuri, Maziar
Date
2019
Description
Lithium-ion batteries (LIBs) have revolutionized the portable electronic devices and electric vehicles (EV) and because of this huge demand,...
Show moreLithium-ion batteries (LIBs) have revolutionized the portable electronic devices and electric vehicles (EV) and because of this huge demand, it is important to meet high power, high specific energy, and long cycle life. All mentioned characteristics are directly related to the choice of anode and cathode electrodes. Currently, graphite is used as anode, while lithium cobalt oxide serves as cathode dominantly. Although graphite can deliver ~ 370 mA h g-1 capacity without significant capacity decay for several cycles, however it is not enough to fulfill the requirements for many applications. Silicon with the theoretical capacity of about 10 times higher than graphite is a promising anode. However, this material suffers from huge volume expansion during cycling in addition to its intrinsic low conductivity. From the cathode viewpoint, the need for materials with less cobalt content is necessary. The resources for cobalt element is very limited while the price of cobalt increasing. Furthermore, cobalt is known as toxic element. Therefore, substitution of cobalt with other elements such as manganese and nickel is necessary. Lithium nickel manganese cobalt oxide (NMC) cathode family materials are introduced following this idea.Here in this thesis, two different approaches are introduced to harness the problems associated with silicon anodes. The first approach is the core/shell design and the second one is the silicon/graphite nanocomposite with tailored structure and engineered voids. Both of these designs can be synthesized easily without complicatedsynthesis steps and harmful chemicals. They have the potential of being commercialized and they do not need expensive equipment. The silicon anodes have been tested successfully in the half-cell coin cells.As for the cathode side, two different members of NMC family materials (NMC333 and NMC532) have been tested. To enhance their electrochemical properties and rate capabilities, a facile surface modification using phosphoric acid was employed. This technique resulted in the formation of thin lithium phosphate coating around the particle. The electrodes performed very well in half-cell configuration. It is expected by utilizing the proposed cathode and anode materials in full-cell set up, a high performance battery with fast charge ability is obtained.
Show less
Effects of the Silicon Content on the Dimensional Changes of Electrodes for Lithium-ion Cells: An Electrochemical Dilatometry Study
Title
Effects of the Silicon Content on the Dimensional Changes of Electrodes for Lithium-ion Cells: An Electrochemical Dilatometry Study
Creator
Rodrigues Prado, Andressa Yasmim
Date
2021
Description
The continuous growth of the electric vehicle market has significantly increased the demand for Li-ion batteries (LIBs). However, state-of-the...
Show moreThe continuous growth of the electric vehicle market has significantly increased the demand for Li-ion batteries (LIBs). However, state-of-the-art LIBs are not yet able to meet the EV industry demand for high energy density and long cycle life rechargeable batteries, prompting efforts to improve the performance of Li-ion cells. In this context, silicon became the most promising next-generation active material for LIBs negative electrodes, especially because Si can significantly increase the lithium storage capacity of the commonly available anodes. Nonetheless, commercialization of Si-based electrodes has been hindered by the poor electrochemical performance of these electrodes, which is mainly attributed to the severe volumetric changes in the silicon particles related to the electrochemical reactions with Li. Since the electrodes are composites with a complex combination of various materials interspaced by pores, the electrode-level swelling may differ significantly from the particle-scale expansion. Furthermore, an increase in electrode thickness due to silicon expansion can have a direct effect on how Li-ion cells are designed, as the accommodation of electrode dilation requires additional cell space to prevent significant dynamic stresses. Thus, the actual volumetric energy density of a LIB cell depends on the electrode swelling, since the higher the magnitude of the electrode expansion, the lower the gains in energy density. Monitoring the electrode dilation is just as important as the electrochemical evaluation when designing cells with Si-based anodes.In this work, we use high-resolution operando electrochemical dilatometry to quantify the (de)lithiation-induced expansion/contraction of silicon, blended silicon-graphite and graphite electrodes, upon electrochemical cycling. We evaluate the relationship between electrode capacity and dilation and observe that while the lithiation capacity improved with increasing the silicon content, the electrode swelling is highly aggravated. For silicon-rich anodes, the electrode dilation can be higher than 300%, and the expansion profile consists of a combination of slow swelling at low levels of lithiation followed by an accelerated increase at higher lithium contents. This non-linear dilation allows for narrowing the swelling by limiting the electrode capacity. In addition, we investigate how electrode properties, such as porosity, affect the dilation profile, and quantify the irreversible expansion of the electrodes. Finally, we discuss some of the challenges associated with the dilatometry technique and suggest experimental approaches for obtaining consistent and reliable data.
Show less