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PHOTOCATHODE TUNABILITY: THE PHOTOEMISSIVE PROPERTIES OF ULTRA-THIN MULTILAYERED MgO/Ag/MgO FILMS SYNTHESIZED BY PULSED LASER DEPOSITION
Title
PHOTOCATHODE TUNABILITY: THE PHOTOEMISSIVE PROPERTIES OF ULTRA-THIN MULTILAYERED MgO/Ag/MgO FILMS SYNTHESIZED BY PULSED LASER DEPOSITION
Creator
Velazquez, Daniel Gomez
Date
2015, 2015-05
Description
Much of the early development of photocathode materials was aimed at the growth of photoemissive thin films with low work function, and high...
Show moreMuch of the early development of photocathode materials was aimed at the growth of photoemissive thin films with low work function, and high quantum efficiency (QE). It has been shown, both theoretically and experimentally, that metal-insulator junctions can lead to the modification of the work function and QE for coverages of a few monolayers of metal oxides on metallic substrates. However, the production of electron beams suitable for new photoinjector technologies in many instances requires low emittance beams from the cathode itself. Often the cathode intrinsic emittance plays an important role in new e-gun designs. A demonstration of the ability to control photoemissive properties by engineering the band structure of a photocathode could provide a pathway to meet the demands of new photoinjector technologies. Nemeth et al. [Phys. Rev. Lett. 104, 046801 (2010)] used density functional theory (DFT) to model the properties of a multilayered structure of MgO/Ag(001)/MgO with 4 monolayers of Ag(001) flanked by n monolayers (ML) of MgO. Their model indicated that it is possible to reduce the emittance of a photoemitted electron beam when the thickness n of the MgO layers is 2 or 3 monolayers because the surface band structure exhibits a narrowing of the density of occupied states in momentum near the Γ-point neighboring the Fermi Level. The theoretical prediction concerning the emission properties of these multilayers structures was tested by fabricating them, and then characterizing their emission properties. Synthesis of multilayered MgO/Ag/MgO films was performed using a custom-built pulsed laser deposition (PLD) system. In-situ growth monitoring was carried out by Reflection High-Energy Electron Diffraction (RHEED). Ex-situ techniques such as Scanning Tunneling Microscopy (STM), Scanning Electron Microscopy/Energy Dispersive Spectroscopy (EDS) and Photoelectron Spectroscopy (PES) were used to show the formation of the crystalline and chemical structure of the multilayered films. A Kelvin Probe/photocurrent-detector system, custom-built for this research, was used to measure the work function and QE of the samples. Angle Resolved Photoelectron Spectroscopy was used to measure the angular photoelectron yield. Simultaneous reduction of work function and increase of QE was observed for (001) oriented multilayers of various thicknesses with respect to that of a bare Ag/MgO(001) surface. Work function measurements of multilayers of various thicknesses in the (111) orientation also registered a monotonic reduction with respect to that of a bare Ag/Si(111) surface. Angular emission was compared for a MgO/Ag/MgO multilayer (thicknesses of 3 ML/4 ML/3 ML) sample and Ag/MgO(001). Emission analysis of the angle-resolved photoelectron spectra shows a net change in the angular emission with high kinetic energy electron density shifted toward surface-normal emission. Experimental results were consistent with theoretical predictions, which open the promising possibility of customizing emission properties by direct manipulation of the surface band structure of the emitter.
Ph.D. in Physics, May 2015
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