A foam is a system consisting of a concentrated dispersion of gas bubbles in a liquid. Foams are encountered in many industries such as food,... Show moreA foam is a system consisting of a concentrated dispersion of gas bubbles in a liquid. Foams are encountered in many industries such as food, agriculture, chemicals, petroleum, and paper manufacturing. Aqueous foams are formed by using surfactants or nano-colloidal particles. Thin liquid films containing surfactant micelles or other nano-colloidal particles are considered to be the key structural elements of foams containing gas and liquid. We thus probed the effects of the micellar concentration and the film size (area) on the stability of a dry bulk foam by studying the stability of a single foam lamella containing micelles; this is so we can establish the importance of the micellar structuring phenomenon and the foam film size (area) affecting the bulk foam stability. The film stratification phenomenon (stepwise film thinning) was experimentally observed by the reflected light microinterferometry. The stepwise layer-by-layer decrease of film thickness is due to the appearance and growth of dark spot (of one layer less film thickness) in the film. We used the two-dimensional diffusion model to model the dynamics of dark spot expansion considering the apparent diffusion coefficient and the film size. Based on this model, we carried out a parametric study depicting the effects of film thickness (or the number of micellar layers) and film area on the rate of dark spot expansion. Many practical applications involving three-phase foams (aqueous foams containing oil) commonly employ surfactants at several times their critical micelle concentration (CMC). We investigated the influence of both the dispersed and solubilized oils, and the surfactant concentration (above CMC) on the stability of an aqueous foaming system. In foam stability, the relative importance of the dispersed oil versus oil solubilized within the micelles depends on the stability of the aqueous asymmetric (i.e., pseudoemulsion) film between the oil and the air-water interface and the second virial coefficient. Also, the micellar structuring phenomenon tests using the single foam lamella revealed that the multi-layering structure was well pronounced in the absence of the solubilized oil; as a consequence, the foam lamellae thinned slowly layer-by-layer and the oil solubilized in micelles weakened the micellar structure formation. The foam lamellae thinned faster, making the foam less stable. Ph.D. in Chemical Engineering, May 2016 Show less
