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- Title
- Raman Spectroscopy as a Probe of Surface Defects in Nb for SRF Cavities
- Creator
- Hommerding, Emily, Ford, Denise, Cao, Chaoyue, Bishnoi, Sandra, Zasadzinski, John
- Date
- 2012, 2012
- Description
-
Superconducting RF (SRF) cavities made of Nb are an enabling device for future linear accelerators. Recently it has been demonstrated that hot...
Show moreSuperconducting RF (SRF) cavities made of Nb are an enabling device for future linear accelerators. Recently it has been demonstrated that hot spots in SRF cavities, which diminish performance, are correlated with a high density of defects (etch pits) especially near grain boundaries. For a pit to cause local heating, it is likely that near-surface impurities, e.g. hydrides or oxides are leading to suppressed superconductivity. New probes are needed to measure such complexes. Here we present Raman spectroscopy. Raman is a fast, nonperturbative method that can measure the vibrational modes of Nb-O and Nb-H complexes by inelastic light scattering. These can then be compared to molecular dynamics simulations to identify oxide and hydride phases. The probing depth of Raman is estimated from the skin depth of the 785 nm laser in the bulk Nb ~ 10-20 nm. This is a reasonable fraction of the superconducting penetration depth ~ 45 nm. Simulating manufacturing processes of SRF cavities may shed light on the origins and composition of hot spots, and their relationship with defects in the material. Defects such as pits, whose origins are yet unknown, are found in the hot spots of completed cavities. Raman spectroscopy is used here to identify changes in the surface chemistry after manipulations such as creating artificial pits, exposing the material to chemical etching, or cold-working the material. BCP exposure and cold-working are common to the SRF manufacturing process.
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- Title
- Improving Niobium Superconducting Radio-Frequency Cavities by Studying Tantalum
- Creator
- Helfrich, Halle
- Date
- 2023
- Description
-
Niobium superconducting radio-frequency (SRF) cavities are widely used accelerating structures. Improvements in both quality factor, Q0, and...
Show moreNiobium superconducting radio-frequency (SRF) cavities are widely used accelerating structures. Improvements in both quality factor, Q0, and maximum accelerating gradient, Eacc, have been made to SRF cavities by introducing new processing techniques. These breakthroughs include processes such as nitrogen doping(N-Doping) and infusion, electrochemical polishing (EP) and High Pressure Rinsing (HPR). [1] There is still abundant opportunity to improve the cavities or, rather, the material they’re primarily composed of: niobium. A focus here is the role the native oxide of Nb plays in SRF cavity performance. The values of interest in a given cavity are its quality factor Q0, maximum accelerating gradient Eacc and surface resistance Rs . This work characterizes Nb and Ta foils prepared under identical conditions using X-ray photoelectron spectroscopy (XPS) to compare surface oxides and better understand RF loss mechanisms in Nb SRF cavities and qubits. It is well established that Ta qubits experience much longer coherence times than Nb qubits, which is probably due to the larger RF losses in Nb oxide. By studying Tantalum, an element similar to Niobium, the mechanisms of the losses that originate in the oxide and suboxide layers present on the surface of Nb cavities might finally be unlocked. We find noticeable differences in the oxides of Nb and Ta formed by air exposure of clean foils. In particular, Ta does not display the TaO2 suboxide in XPS, while Nb commonly shows NbO2. This suggests that suboxides are an additional contributor of RF losses. We also suggest that thin Ta film coatings of Nb SRF cavities may be a way of increasing Q0. It is in the interest of the accelerator community to fully understand the surface impurities present in Nb SRF cavities so that strategies for mitigating the effects can be proposed.
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