To improve the wear resistance of titanium and extend its service life, coating boron nitride thin films on the surface of titanium matrix was... Show moreTo improve the wear resistance of titanium and extend its service life, coating boron nitride thin films on the surface of titanium matrix was studied in this work. To obtain surface property enhancement, the samples were coated by isothermal sintering at 1000°C – 1400°C in a vacuum furnace for 2h, 4h or 6h. The microstructure of the thin film was investigated employing X-ray diffraction (XRD), scanning electron microscopy (SEM), and energy dispersive spectroscopy (EDS). To identify the composition of interlayers between BN and Ti, EDS analysis was run through the whole reaction zone. It showed that the BN was being consumed, titanium borides (TiB and TiB2), titanium nitride (TiN1-x), and solid solution of nitrogen in titanium (α-Ti (N)) layers formed at the interface between the BN coating and Ti matrix. Correspondingly, the XRD analysis indicated that TiB, TiB2, TiN, and α-Ti(N) phases were presented in good agreement with the EDS result. The layers grew fast in the sintering process which benefited from the fine grain size and highly oriented layers grown in the reaction zone. However, the well-known parabolic diffusional growth is only part of mechanisms for explaining the reactiondiffusion kinetics. The diffusion paths were obtained from the phase sequences at the interface between BN and Ti and thus could be represented on the isothermal section of the B-N-Ti ternary diagram. Moreover, the influence of the sintering temperature and the length of the actual sintering period on the layer sequences and thickness of the reaction zone were investigated. The micro-hardness test results showed that the Ti matrix with deposited BN thin films exhibited significant increased surface hardness. Obviously, the surface hardness xiii rose along with sintering temperature and holding time, and the hardness could be improved over 50%. M.S. in Materials Science and Engineering, December 2013 Show less
