creator Prabhukumar, Giridhar advisor Pagilla, Krishna R. Urban stormwater runoff is a major contributor of pollutants to nearshore beach water of Lake Michigan and other water bodies. Reduction of pollutants levels to within safe limits in urban runoff from near shore areas by means of filtration using low-impact reactive multi-media systems is the subject of research in this dissertation. The key research issues addressed are the identification of effective filter materials and laboratory-scale testing of the selected materials for permeable reactive filter systems (PRFS) that are feasible for installation in urban environment. The focus was to evaluate different media materials for removal of total suspended solids (TSS), nutrients (nitrate and phosphate), heavy metals (Cd, Cr, Cu, Pb, Ni and Zn), polycyclic aromatic hydrocarbons (naphthalene and phenanthrene) and microbial (E. coli.) contaminants from stormwater runoff to levels below standard discharge criteria. Eight different media materials were initially selected, including calcite, anthracite coal, zeolite, sand, iron-oxide coated sand (IOCS), iron filings, perlite and biochar. Of these, calcite (C), zeolite (Z), sand (S) and iron filings (Fe0) were screened based on preliminary column experiment results and used for further studies. Physical and chemical characterization studies were carried out to understand the material properties. Contaminant attenuation studies with lab-scale column experiments for the four individual media materials (C, Z, S and Fe0) were conducted with synthetic stormwater solution containing all the aforementioned pollutants. Results showed that calcite and sand were efficient in TSS, nutrients and polycyclic aromatic hydrocarbons (PAHs) removal, zeolite was efficient for metals removal and the only material that was able to lower E. coli level to below its safe xv limit of 126 most probable number (MPN) per 100ml, and iron filings was efficient in nutrients and metals removal. Column experiments were also conducted with three mixed media compositions, C-Z-S, C-Z-Fe0 and C-Z-S-Fe0. The results indicated that a multi-media based filtration system can perform efficiently to treat a wide range of pollutants and runoff flow conditions. Finally, several conceptual designs for PRFS were proposed that are suitable for application at various urban locations. Submitted by Liana Khananashvili (khananashvili@iit.edu) on 2013-11-05T21:23:17Z No. of bitstreams: 2 PhD_Thesis_Giridhar Prabhukumar_6Mayl2013.pdf: 6840213 bytes, checksum: 9676932d3230234bac8f3999d5064f31 (MD5) Signed_TitlePage_Giridhar Prabhukumar_6May2013.pdf: 131781 bytes, checksum: f0985e78759d12244b012427900ce2ee (MD5) Made available in DSpace on 2013-11-05T21:23:17Z (GMT). No. of bitstreams: 2 PhD_Thesis_Giridhar Prabhukumar_6Mayl2013.pdf: 6840213 bytes, checksum: 9676932d3230234bac8f3999d5064f31 (MD5) Signed_TitlePage_Giridhar Prabhukumar_6May2013.pdf: 131781 bytes, checksum: f0985e78759d12244b012427900ce2ee (MD5) Previous issue date: 2013-05 PH.D in Environmental Engineering, May 2013 2013 2013-05 http://hdl.handle.net/10560/3126 en Dissertation born digital application/pdf In Copyright http://rightsstatements.org/page/InC/1.0/ Restricted Access CAEE / Civil, Architectural, and Environmental Engineering Illinois Institute of Technology Affiliated department