SYNTHESIS AND CHARACTERIZATION OF MG, NB, TI-DOPED LINIO2 CATHODE MATERIAL FOR LI-ION BATTERIES

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Description

In this project, the influence of several metal doping on the electrochemical properties of LiNiO2 materials was analyzed. The doping method is aiming to improve the stability of the layered structure and inhibit the mixing of nickel and lithium by enhancing the structural stability of the... Show moreIn this project, the influence of several metal doping on the electrochemical properties of LiNiO2 materials was analyzed. The doping method is aiming to improve the stability of the layered structure and inhibit the mixing of nickel and lithium by enhancing the structural stability of the layered material and replacing part of Ni with other metals in the process of intercalation/deintercalation, thereby promoting the cyclic performance and reversible capacity. The LiNiO2 powder doped with Nb, Ti and Mg is denoted as Li0.96Ni0.9Nb0.06Ti0.04Mg0.02O2 or, in short, metal-doped LiNiO2. The synthesis of the metal-doped LiNiO2 powder consists of mixing the lithium and nickel sources with various metal oxides and then being subjected to high-energy ball milling for 10 hours, followed by heating for 20 h in a metallic tube furnace at 680℃ with flowing oxygen atmosphere. The undoped LiNiO2 powder synthesized using the same process and conditions was compared with the doped LiNiO2 powder. In order to understand the doping mechanism, field emission scanning electron microscopy (FESEM), energy dispersive spectroscopy (EDS), and X-ray diffraction (XRD) were used to analyze the morphology, composition and crystal structure of the final product. Benefiting from the Mg, Nb, and Ti doping, the doped LiNiO2 exhibited a high reversible capacity of 130.56 mAh g-1, higher than that of undoped LiNiO2 (95.02 mAh g-1) under the 0.1C charge/discharge rate in the voltage window between 2.5 and 4.2 V. Further, the doped LiNiO2 has 86% of capacity retention over 100 cycles, better than undoped LiNiO2 (only 44% of capacity retention) under the 0.5C charge/discharge rate between 2.5 and 4.2 V. Show less

Details
Department

MMAE / Mechanical, Materials, and Aerospace Engineering

Title

SYNTHESIS AND CHARACTERIZATION OF MG, NB, TI-DOPED LINIO2 CATHODE MATERIAL FOR LI-ION BATTERIES

Institution

Illinois Institute of Technology

Creator(s)

Tian, Yiwen

Advisor(s)

Shaw, Leon L

Date

2022

Description

In this project, the influence of several metal doping on the electrochemical properties of LiNiO2 materials was analyzed. The doping method is aiming to improve the stability of the layered... Show moreIn this project, the influence of several metal doping on the electrochemical properties of LiNiO2 materials was analyzed. The doping method is aiming to improve the stability of the layered structure and inhibit the mixing of nickel and lithium by enhancing the structural stability of the layered material and replacing part of Ni with other metals in the process of intercalation/deintercalation, thereby promoting the cyclic performance and reversible capacity. The LiNiO2 powder doped with Nb, Ti and Mg is denoted as Li0.96Ni0.9Nb0.06Ti0.04Mg0.02O2 or, in short, metal-doped LiNiO2. The synthesis of the metal-doped LiNiO2 powder consists of mixing the lithium and nickel sources with various metal oxides and then being subjected to high-energy ball milling for 10 hours, followed by heating for 20 h in a metallic tube furnace at 680℃ with flowing oxygen atmosphere. The undoped LiNiO2 powder synthesized using the same process and conditions was compared with the doped LiNiO2 powder. In order to understand the doping mechanism, field emission scanning electron microscopy (FESEM), energy dispersive spectroscopy (EDS), and X-ray diffraction (XRD) were used to analyze the morphology, composition and crystal structure of the final product. Benefiting from the Mg, Nb, and Ti doping, the doped LiNiO2 exhibited a high reversible capacity of 130.56 mAh g-1, higher than that of undoped LiNiO2 (95.02 mAh g-1) under the 0.1C charge/discharge rate in the voltage window between 2.5 and 4.2 V. Further, the doped LiNiO2 has 86% of capacity retention over 100 cycles, better than undoped LiNiO2 (only 44% of capacity retention) under the 0.5C charge/discharge rate between 2.5 and 4.2 V. Show less

Type

Thesis

File type

application/pdf

Subject

Materials Science
Diffraction
H3PO4 surface treatment
Li/Ni cation mixing
LiNiO2
Lithium battery
Mg Ti and Nb substitution

Access

Restricted Access

Rights

In Copyright
http://rightsstatements.org/page/InC/1.0/

Identifier

http://hdl.handle.net/10560/islandora:1024960

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